hydrogen in tetrahydrofuran H2 was introduced into a flask containing a THF soln. of U-complex and 1-pentene (U-complex/H2/1-pentene = 0.1:2:6), soln. was stirred for 15 h at 20°C; 30percent of 1-pentene was converted into n-pentane; (1)H NMR analysis of the reaction mixt., pentane was detd. by GC anal.;
参考文献
Foyentin, Muriel; Folcher, Gerard; Ephritikhine, Michel
Journal of Organometallic Chemistry, 1987 , vol. 335, p. 201 - 206
lt;Pd4(SnCl2)2(SnCl3)8gt;(5-) in ethanol T=59.9°C; P=37503 Torr; 2 h; selectivity in catalytic transformation; Product distribution;
参考文献
Borunova, N. V.; Antonov, P. G.; Antseva, N. V.; Sharf, V. Z.; Kukushkin, Yu. N.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 2 p. 265 - 268,224 - 227
