in tetrahydrofuran Electrolysis; electrolyte 0.4 M LiClO4 in THF; electrolysis carried out galvanostatically at 25-28°C in atm. of dry N2; hexane added to electrolyte, ppt. filtered off, filtrate analyzed for the products by GC;
iodine in octane; diethyl ether Mg etching with small iodine crystal, Et2O addn., n-butylchloride soln. in n-octane slow addn. on heating, reflux till Mg dissolution; filtration, washing (n-octane), drying;
参考文献
Stukalov, Denis V.; Zakharov, Vladimir A.; Potapov, Alexander G.; Bukatov, Gennady D.
Journal of Catalysis, 2009 , vol. 266, # 1 p. 39 - 49
