T=326.9°C; P=0.01 - 0.06 Torr; Irradiationthermal decomposition; other temperatures; variation of yield on fluence and pulse duration; KineticsProduct distribution;
参考文献
Journal of Physical Chemistry, , vol. 86, # 1 p. 41 - 49
1: With 1,3-bis-(diphenylphosphino)propane; potassium carbonate; palladium diacetate in water T=90°C; Heck reaction; 1.33333 h; 2: With hydrogenchloride in water; ethyl acetate T=20°C; Further stages.;
参考文献
Journal of Organic Chemistry, , vol. 72, # 17 p. 6390 - 6396
carbon monoxide in neat (no solvent) High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;
参考文献
Kron, Johanna; Schubert, Ulrich
Journal of Organometallic Chemistry, 1989 , vol. 373, p. 203 - 220
carbon monoxide in diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;
参考文献
Kron, Johanna; Schubert, Ulrich
Journal of Organometallic Chemistry, 1989 , vol. 373, p. 203 - 220
