2-甲基-1,8-辛烷二醇合成路线 （共 4 条）
反应条件
diisobutylaluminium hydride in ethanol; toluene T=-70 - -20°C; Reduction; 1 h;
参考文献
Di Deo, Milena; Marcantoni, Enrico; Torregiani, Elisabetta; Bartoli, Giuseppe; Bellucci, Maria Cristina; Bosco, Marcella; Sambri, Letizia
Journal of Organic Chemistry, 2000 , vol. 65, # 9 p. 2830 - 2833
反应条件
1: 87 percent / diisobutylaluminium hydride / CH2Cl2 / 1 h / -78 °C 2: 72 percent / sodium hydride / tetrahydrofuran / 1 h / 20 °C 3: 84 percent / H2 / Pd/C / ethyl acetate / 4 h / 20 °C / 760.05 Torr 4: 77 percent / diisobuylaluminium hydride / ethanol; toluene / 1 h / -70 - -20 °C View Scheme
参考文献
Tsunoda, Tetsuto; Uemoto, Kaori; Nagino, Chisato; Kawamura, Megumi; Kaku, Hiroto; Ito, Sho
Tetrahedron Letters, 1999 , vol. 40, # 41 p. 7355 - 7358
反应条件
1: 72 percent / sodium hydride / tetrahydrofuran / 1 h / 20 °C 2: 84 percent / H2 / Pd/C / ethyl acetate / 4 h / 20 °C / 760.05 Torr 3: 77 percent / diisobuylaluminium hydride / ethanol; toluene / 1 h / -70 - -20 °C View Scheme
参考文献
Tsunoda, Tetsuto; Uemoto, Kaori; Nagino, Chisato; Kawamura, Megumi; Kaku, Hiroto; Ito, Sho
Tetrahedron Letters, 1999 , vol. 40, # 41 p. 7355 - 7358
反应条件
1: 84 percent / H2 / Pd/C / ethyl acetate / 4 h / 20 °C / 760.05 Torr 2: 77 percent / diisobuylaluminium hydride / ethanol; toluene / 1 h / -70 - -20 °C View Scheme
参考文献
Tsunoda, Tetsuto; Uemoto, Kaori; Nagino, Chisato; Kawamura, Megumi; Kaku, Hiroto; Ito, Sho
Tetrahedron Letters, 1999 , vol. 40, # 41 p. 7355 - 7358
