ammonia; hydrogen; palladium 10 on activated carbon in water P=3750.38 Torr; pH=9; 16 h;

5 Pd(II)/C(eggshell); hydrogen in ethanol; water T=25 - 30°C; P=1838.93 - 2206.72 Torr; 3 h; Autoclave;

hydrogen; palladium on activated charcoal in ethanol 6 h; Ambient temperature;

hydrogen; palladium on activated charcoal in ethanol T=30°C; 1 h; Yield given;

暂无反应条件数据

in acetone T=0 - 50°C; 4 h; Electrodialysis; Product distribution / selectivity;

1.1: thionyl chloride / 13 h / 0 - 25 °C / Inert atmosphere 2.1: sodium hydroxide / water / pH 7.5 - 8 2.2: 0.5 h / 0 °C 2.3: 3 h / 25 °C 3.1: 5 Pd(II)/C(eggshell); hydrogen / ethanol; water / 3 h / 25 - 30 °C / 1838.93 - 2206.72 Torr / Autoclave View Scheme

1.1: sodium hydroxide / water / pH 7.5 - 8 1.2: 0.5 h / 0 °C 1.3: 3 h / 25 °C 2.1: 5 Pd(II)/C(eggshell); hydrogen / ethanol; water / 3 h / 25 - 30 °C / 1838.93 - 2206.72 Torr / Autoclave View Scheme

1.1: lithium diisopropyl amide / 0.5 h / 0 - 5 °C 1.2: 4 h / 0 - 30 °C 2.1: hydrogenchloride / diethyl ether / 30 °C 3.1: 12 h / 100 °C 4.1: 10 palladium on activated charcoal; hydrogen / 10 h / 30 °C 5.1: thionyl chloride / 13 h / 0 - 25 °C / Inert atmosphere 6.1: sodium hydroxide / water / pH 7.5 - 8 6.2: 0.5 h / 0 °C 6.3: 3 h / 25 °C 7.1: 5 Pd(II)/C(eggshell); hydrogen / ethanol; water / 3 h / 25 - 30 °C / 1838.93 - 2206.72 Torr / Autoclave View Scheme

1.1: toluene-4-sulfonic acid / toluene / 1 h / 110 °C 2.1: lithium diisopropyl amide / 0.5 h / 0 - 5 °C 2.2: 4 h / 0 - 30 °C 3.1: hydrogenchloride / diethyl ether / 30 °C 4.1: 12 h / 100 °C 5.1: 10 palladium on activated charcoal; hydrogen / 10 h / 30 °C 6.1: thionyl chloride / 13 h / 0 - 25 °C / Inert atmosphere 7.1: sodium hydroxide / water / pH 7.5 - 8 7.2: 0.5 h / 0 °C 7.3: 3 h / 25 °C 8.1: 5 Pd(II)/C(eggshell); hydrogen / ethanol; water / 3 h / 25 - 30 °C / 1838.93 - 2206.72 Torr / Autoclave View Scheme