((1E,3e)-5-溴-1,3-戊二烯)-苯合成路线 （共 6 条）
反应条件
phosphorus tribromide in diethyl ether T=0°C; 1.5 h;
参考文献
Kim, Dwight D.; Lee, Suk Joong; Beak, Peter
Journal of Organic Chemistry, 2005 , vol. 70, # 14 p. 5376 - 5386
反应条件
1: 85 percent / HCl / diethyl ether / 20 h 2: 55 percent / DIBAL-H / toluene / 3 h / 45 °C 3: 80 percent / PBr3 / diethyl ether / 1.5 h / 0 °C View Scheme
参考文献
Huang, Yange; Fananas-Mastral, Martin; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2013 , vol. 49, # 32 p. 3309 - 3311
反应条件
1: 55 percent / DIBAL-H / toluene / 3 h / 45 °C 2: 80 percent / PBr3 / diethyl ether / 1.5 h / 0 °C View Scheme
参考文献
Huang, Yange; Fananas-Mastral, Martin; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2013 , vol. 49, # 32 p. 3309 - 3311
反应条件
1: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C / |Inert atmosphere 2: phosphorus tribromide / diethyl ether / 0 °C / |Inert atmosphere; |Darkness View Scheme
参考文献
West, Thomas H.; Daniels, David S. B.; Slawin, Alexandra M. Z.; Smith, Andrew D.
Journal of the American Chemical Society, 2014 , vol. 136, # 12 p. 4476 - 4479
反应条件
1: dichloromethane / 20 - 25 °C / |Inert atmosphere 2: diisobutylaluminium hydride / dichloromethane; toluene / 1.5 h / -78 °C / |Inert atmosphere 3: phosphorus tribromide / diethyl ether / 0 °C / |Inert atmosphere; |Darkness View Scheme
参考文献
West, Thomas H.; Daniels, David S. B.; Slawin, Alexandra M. Z.; Smith, Andrew D.
Journal of the American Chemical Society, 2014 , vol. 136, # 12 p. 4476 - 4479
反应条件
(R)-(S)-PPF-PCy2; cupric bromide-dimethyl sulfide in dichloromethane
1 h; Inert atmosphere; Reagent/catalystSolvent; enantioselective reaction;
参考文献
Huang, Yange; Fananas-Mastral, Martin; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2013 , vol. 49, # 32 p. 3309 - 3311
