2-甲基-6-(4,4,5,5-四甲基-1,3,2-二噁硼烷-2-基)吡啶合成路线 （共 4 条）
反应条件
catalyst: [Ir(COD)Cl]2/2bpy in further solvent(s) under Ar; (C5H4N)CH3 (60 mmol) added to pinacolborane (2 mmol) and 1.5 mol percent (Ir(COD)Cl)2 and 1.5 molpercent bpy; stirred (80°C, 6 h); solvent removed (vac., room temp.); residue chromd. (silica gel, CH2Cl2);
参考文献
Mertins, Kristin; Zapf, Alexander; Beller, Matthias
Journal of Molecular Catalysis A: Chemical, 2004 , vol. 207, # 1 p. 21 - 25
反应条件
(iPrPNP)CoCH2SiMe3 in tetrahydrofuran T=80°C; 24 h; Inert atmosphereGlovebox; Overall yield = 92 percent; Overall yield = 0.111 g;
参考文献
Journal of the American Chemical Society, , vol. 136, # 11 p. 4133 - 4136
反应条件
catalyst: [Ir(COD)Cl]2/2bpy in further solvent(s)
under Ar; (C5H4N)CH3 (60 mmol) added to pinacolborane (2 mmol) and 1.5 mol percent (Ir(COD)Cl)2 and 1.5 molpercent bpy; stirred (80°C, 6 h); solvent removed (vac., room temp.); residue chromd. (silica gel, CH2Cl2);
参考文献
Mertins, Kristin; Zapf, Alexander; Beller, Matthias
Journal of Molecular Catalysis A: Chemical, 2004 , vol. 207, # 1 p. 21 - 25
反应条件
(iPrPNP)CoCH2SiMe3 in tetrahydrofuran
T=80°C; 24 h; Inert atmosphereGlovebox; Overall yield = 92 percent; Overall yield = 0.111 g;
参考文献
Obligacion, Jennifer V.; Semproni, Scott P.; Chirik, Paul J.
Journal of the American Chemical Society, 2014 , vol. 136, # 11 p. 4133 - 4136
