1: hydrogen chloride / Behandeln des Reaktionsprodukts mit Brom, Behandeln des erhaltenen Dibromids mit Hexylmagnesiumbromid in Aether und Erhitzen des danach isolierten Reaktionsprodukts mit Kaliumhydroxyd 2: diethyl ether View Scheme
参考文献
Hill et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 352
1.1: MeLi / tetrahydrofuran; diethyl ether / 0.25 h / -10 °C 1.2: 90 percent / tetrahydrofuran; diethyl ether / 2 h / -40 - 20 °C 2.1: 89 percent / TBAF / tetrahydrofuran 3.1: 85 percent / H2; TEA / Pd-BaSO4 / 0.75 h / 760 Torr 4.1: 72 percent / Jones' reagent / acetone / 0.5 h / -10 °C View Scheme
参考文献
Schwartz, Brett D.; McErlean, Christopher S. P.; Fletcher, Mary T.; Mazomenos, Basilis E.; Konstantopoulou, Maria A.; Kitching, William; De Voss, James J.
Organic Letters, 2005 , vol. 7, # 6 p. 1173 - 1176
in 1,2-dichloro-ethane T=0°C; 1 h; competitive reactions between aliphatic and α,β-unsaturated, aliphatic and aromatic, unbranched and α,β-dialkylated aldehydes and acetals.; Product distributionMechanism;
