N,N'-二甲基乙二胺合成路线 （共 190 条）
反应条件
triethylamine in benzene
参考文献
Simmler,W.
Chemische Berichte, 1963 , vol. 96, p. 349 - 356
参考文献
Gol'din,G.S. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1977 , vol. 47, p. 1666,1527
参考文献
Beugelmans, Rene; Benadjila-Iguertsira, Leila; Chastanet, Jacqueline; Negron, Guillermo; Roussi, Georges
Canadian Journal of Chemistry, 1985 , vol. 63, p. 725 - 734
反应条件
potassium phosphate; CuI in N-dodecane; ethyl acetate; toluene
参考文献
Buchwald, Stephen L.; Klapars, Artis; Antilla, Jon C.; Job, Gabriel E.; Wolter, Martina; Kwong, Fuk Y.; Nordmann, Gero; Hennessy, Edward J.
Patent: US2003/65187 A1, 2003 ;
参考文献
Ellingboe, John W.; Spinelli, Walter; Winkley, Michael W.; Nguyen, Thomas T.; Parsons, Roderick W.; et al.
Journal of Medicinal Chemistry, 1992 , vol. 35, # 4 p. 705 - 716
反应条件
boron trichloride; triethylamine in tetrahydrofuran; hexane T=20°C; RefluxInert atmosphere;
参考文献
Singidi, Ramakrishna Reddy; Kutney, Amanda M.; Gallucci, Judith C.; Rajanbabu
Journal of the American Chemical Society, 2010 , vol. 132, # 37 p. 13078 - 13087
反应条件
in Petroleum ether boiling under nitrogene; distn.;
参考文献
Gmelin Handbook: B: B-Verb.1, 2.5.1.3, page 122 - 126
反应条件
potassium cyanide; CuI in N-dodecane; ethyl acetate; toluene
参考文献
Buchwald, Stephen L.; Klapars, Artis; Antilla, Jon C.; Job, Gabriel E.; Wolter, Martina; Kwong, Fuk Y.; Nordmann, Gero; Hennessy, Edward J.
Patent: US2003/65187 A1, 2003 ;
反应条件
N(C2H5)3 in hexane byproducts: ((C2H5)3NH)Cl; under N2, addn. of both amines in hexane to a stirred hexane soln. of B-compd. at -30°C, refluxed for 17 h; centrifugation, hexane evapd., fractional distn.;
参考文献
Chemische Berichte, , vol. 127, # 9 p. 1605 - 1612
反应条件
in water addn. of aq. en into aq. soln. of Co complex, pH adjisted to 9 (HCl), heating and stirring (50°C, 2 h); vaolume reduction, repeated column chromy. (Sephadex G-10, SP-Sephadex C-25, aq. 0.2 M KCl), red band collected, volume reduction (vac.), addn. of MeOH, filtration off KCl; (sym-cis isomer obtained from purple-red band by same manner); elem. anal.;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 29, # 9 p. 1567 - 1578
