N,N'-二甲基乙二胺合成路线 （共 190 条）
反应条件
potassium phosphate in 1,4-dioxane; water
参考文献
GENERAL ELECTRIC COMPANY
Patent: US2008/142429 A1, 2008 ;
反应条件
potassium carbonate in 1,4-dioxane; water
参考文献
GENERAL ELECTRIC COMPANY
Patent: US2008/142429 A1, 2008 ;
反应条件
in Petroleum ether stoich. amt., room temp. under nitrogene; distn.;
参考文献
Gmelin Handbook: B: B-Verb.1, 2.5.1.3, page 122 - 126
反应条件
in water T=20°C; 0.0333333 h;
参考文献
Odagami, Takenao; Tsuda, Yuko; Kogami, Yuji; Kouji, Hiroyuki; Okada, Yoshio
Chemical and Pharmaceutical Bulletin, 2009 , vol. 57, # 2 p. 211 - 213
反应条件
n-butyllithium in diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.;
参考文献
Schmid, Guenter; Polk, Michael; Boese, Roland
Inorganic Chemistry, 1990 , vol. 29, p. 4421 - 4429
反应条件
CuI in N-dodecane; ethyl acetate; toluene; N,N,N',N'-tetramethylguanidine
参考文献
Buchwald, Stephen L.; Klapars, Artis; Antilla, Jon C.; Job, Gabriel E.; Wolter, Martina; Kwong, Fuk Y.; Nordmann, Gero; Hennessy, Edward J.
Patent: US2003/65187 A1, 2003 ;
反应条件
in 1,4-dioxane; water T=25°C; var. total amine concentrations; Rate constant;
参考文献
Garcia-Rio, Luis; Iglesias, Emilia; Leis, J. Ramon; Pena, M. Elena; Rios, Ana
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 29 - 37
反应条件
1: With selenium T=20°C; P=750.075 Torr; 2 h; neat (no solvent); 2: With oxygen T=20°C; P=750.075 Torr; 1 h; neat (no solvent);
参考文献
Mizuno, Takumi; Nakai, Takeo; Mihara, Masatoshi
Synthesis, 2010 , # 24 art. no. F15510SS, p. 4251 - 4255
反应条件
cerium (IV) oxide in isopropyl alcohol T=159.84°C; P=3750.38 Torr; 24 h; Autoclave; Solvent;
参考文献
Tamura, Masazumi; Noro, Kensuke; Honda, Masayoshi; Nakagawa, Yoshinao; Tomishige, Keiichi
Green Chemistry, 2013 , vol. 15, # 6 p. 1567 - 1577
反应条件
tetraphosphorus decasulfide; triphenyl antimony oxide in benzene T=100°C; P=36752.9 Torr;
参考文献
Journal of Organic Chemistry, , vol. 57, # 28 p. 7339 - 7342
