反应条件
1: 1) t-BuOK, 2) I2 / 1) EtOH, 1 h, 2) toluene, reflux
2: CuSO4 / benzene / 75 °C
3: aq. NaOH / methanol / 0.5 h / 50 °C
4: 1) diphenyl phosphoroazidate (DPPA), NEt3 / 1) benzene, reflux, 5 h, 2) reflux, 3 h
5: NaNO2, Ac2O, glac.HOAc / 2 h / ice-water bath
6: toluene; methanol / 0.05 h / 23.9 °C / other temperatures, kt/k0, ΔΔH(excit.), ΔΔS(excit.)
View Scheme
参考文献
Warner, Philip; Sutherland, Robert
Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6294 - 6300
