苯并呋喃-2-硼酸甲基亚氨基二乙酸酯合成路线 （共 8 条）
反应条件
sodium hydroxide in tetrahydrofuran; water T=23°C; 0.333333 h;
参考文献
Knapp, David M.; Gillis, Eric P.; Burke, Martin D.
Journal of the American Chemical Society, 2009 , vol. 131, p. 6961 - 6963
反应条件
in not given hydrolysis of appropriate N-methyliminodiacetic acid boronate;
参考文献
Knapp, David M.; Gillis, Eric P.; Burke, Martin D.
Journal of the American Chemical Society, 2009 , vol. 131, p. 6961 - 6963
反应条件
in dimethyl sulfoxide; toluene
8 h; Reflux;
参考文献
THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS; BURKE, Martin, D.; KNAPP, David, M.; GILLIS, Eric, P.
Patent: WO2010/36921 A2, 2010 ;
Location in patent: Page/Page column 34 ;
反应条件
BF4(1-)*C54H36Au3Cl9OP3(1+) in tetrahydrofuran
T=65°C; Inert atmosphere;
参考文献
Chan, Julian M.W.; Amarante, Giovanni W.; Toste, F. Dean
Tetrahedron, 2011 , vol. 67, # 24 p. 4306 - 4312
反应条件
1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 6 h / 20 °C / Inert atmosphere
2: BF4(1-)*C54H36Au3Cl9OP3(1+) / tetrahydrofuran / 65 °C / Inert atmosphere
View Scheme
参考文献
Chan, Julian M.W.; Amarante, Giovanni W.; Toste, F. Dean
Tetrahedron, 2011 , vol. 67, # 24 p. 4306 - 4312
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; potassium phosphate; palladium diacetate in tetrahydrofuran; water
T=60°C; Suzuki coupling; 4.5 h; Inert atmosphere;
参考文献
Chan, Julian M.W.; Amarante, Giovanni W.; Toste, F. Dean
Tetrahedron, 2011 , vol. 67, # 24 p. 4306 - 4312
反应条件
[PdCl2(bis(di-tert-butylphosphino)ferrocene)]; TPGS–750–M; triethylamine in water
T=20°C; Inert atmosphere;
参考文献
Isley, Nicholas A.; Gallou, Fabrice; Lipshutz, Bruce H.
Journal of the American Chemical Society, 2013 , vol. 135, # 47 p. 17707 - 17710
反应条件
1: With dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate in 1,4-dioxane
T=23°C; 0.166667 h; Inert atmosphere;
2: With potassium phosphate; water in 1,4-dioxane
T=23 - 60°C; 6.5 h; Inert atmosphere;
参考文献
Knapp, David M.; Gillis, Eric P.; Burke, Martin D.
Journal of the American Chemical Society, 2009 , vol. 131, p. 6961 - 6963
