4-(9H-咔唑-9-基)苯甲醛合成路线 （共 11 条）
反应条件
18-crown-6 ether; copper; potassium carbonate in 1,2-dichloro-benzene T=200°C; Inert atmosphere;
参考文献
NITTO DENKO CORPORATION; Froehlich, Jesse Dan; Romero, Rebecca; Mochizuki, Amane; Li, Sheng; Negishi, Nobukazu
Patent: US2013/87772 A1, 2013 ;
Location in patent: Paragraph 0076; 0077 ;
反应条件
1: 9-(4-bromophenyl)carbazole With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 2: N,N-dimethyl-formamide in tetrahydrofuran; hexane T=-78 - 20°C; 12 h;
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; KIM, Chi Sik; KIM, Young Gil; CHO, Young Jun; KWON, Hyuck Joo; KIM, Bong Ok; KIM, Sung Min
Patent: WO2011/55911 A1, 2011 ;
Location in patent: Page/Page column 15 ;
反应条件
copper(I) oxide; N,N-dimethyl acetamide T=160°C; Ullmann condensation; 20 h; Inert atmosphere;
参考文献
Yang, Xinchun; Lu, Ran; Gai, Fangyuan; Xue, Pengchong; Zhan, Yong
Chemical Communications, 2010 , vol. 46, # 7 p. 1088 - 1090
反应条件
tri-tert-butyl phosphine; potassium carbonate; palladium diacetate in xylene T=120°C; Condensation; 6 h;
参考文献
Watanabe, Makoto; Nishiyama, Masakazu; Yamamoto, Toshihide; Koie, Yasuyuki
Tetrahedron Letters, 2000 , vol. 41, # 4 p. 481 - 483
反应条件
potassium tert-butylate in N,N-dimethyl-formamide T=110°C; 36 h;
参考文献
Hu, Benlin; Zhuge, Fei; Zhu, Xiaojian; Peng, Shanshan; Chen, Xinxin; Pan, Liang; Yan, Qing; Li, Run-Wei
Journal of Materials Chemistry, 2012 , vol. 22, # 2 p. 520 - 526
反应条件
1.1: potassium carbonate / copper; 18-crown-6 ether / dichlorobenzene 1,2- / 20 h / 200 °C 2.1: n-butyllithium / hexane; tetrahydrofuran / -78 °C 2.2: 12 h / -78 - 20 °C View Scheme
参考文献
Shi, He-Ping; Xu, Lei; Cheng, Ying; He, Jing-Yuan; Dai, Jian-Xin; Xing, Li-Wen; Chen, Bai-Quan; Fang, Li
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2011 , vol. 81, # 1 p. 730 - 738
反应条件
1.1: potassium carbonate / copper; 18-crown-6 ether / dichlorobenzene 1,2- / 20 h / 200 °C 2.1: n-butyllithium / hexane; tetrahydrofuran / -78 °C 2.2: 12 h / -78 - 20 °C View Scheme
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; KIM, Chi Sik; KIM, Young Gil; CHO, Young Jun; KWON, Hyuck Joo; KIM, Bong Ok; KIM, Sung Min
Patent: WO2011/55911 A1, 2011 ;
反应条件
1.1: 18-crown-6 ether; copper; potassium carbonate / N,N-dimethyl-formamide / 24 h / Inert atmosphere; Reflux 2.1: n-butyllithium / diethyl ether; hexane / -78 - 0 °C / Inert atmosphere 2.2: -78 - 20 °C / Inert atmosphere View Scheme
参考文献
Shi, He-Ping; Xu, Lei; Cheng, Ying; He, Jing-Yuan; Dai, Jian-Xin; Xing, Li-Wen; Chen, Bai-Quan; Fang, Li
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2011 , vol. 81, # 1 p. 730 - 738
反应条件
methanol; sodium tetrahydroborate in tetrahydrofuran
T=20°C; 1.5 h;
参考文献
NITTO DENKO CORPORATION; Froehlich, Jesse Dan; Romero, Rebecca; Mochizuki, Amane; Li, Sheng; Negishi, Nobukazu
Patent: US2013/87772 A1, 2013 ;
Location in patent: Paragraph 0078; 0079 ;
反应条件
in dimethyl sulfoxide
T=120°C; 12 h;
参考文献
Shi, He-Ping; Xu, Lei; Cheng, Ying; He, Jing-Yuan; Dai, Jian-Xin; Xing, Li-Wen; Chen, Bai-Quan; Fang, Li
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2011 , vol. 81, # 1 p. 730 - 738
