in deuterated toluene using Schlenk techniques; mixing of solns. of B(C6F5)3 and Al2Me6 in toluene-d8 in NMR tube for 10 min, addn. of soln. of ZrMe2(C5Me5)2 in toluene-d8 at 20°C with ratio B(C6F5)3, Al2Me6 and (C5Me5)2ZrMe2 1:2:1; monitoring by NMR;
参考文献
Mathis, Deborah; Couzijn, Erik P. A.; Chen, Peter
Organometallics, 2011 , vol. 30, # 14 p. 3834 - 3843
in deuterated toluene NMR tube was charged with ligand and Zn-complex, dissolved in toluene-d8, sealed, heated at 60°C for 3 h, volatiles were removed in vacuo, B(C6F5)3 in toluene-d8 was added; monitored by NMR;
Massey, A. G.; Park, A. J.
Journal of Organometallic Chemistry, 1966 , vol. 5, p. 218 - 225
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Gmelin Handbook: F: PerFHalOrg.4, 3.1.3.3.1, page 119 - 119
in toluene (Ar); using Schlenk techniques; charging of glass reactor with soln. of B(C6F5)3 (1 equiv.) in toluene; addn. of Ti(OCHMe2)4 (1 equiv.) at ambient temp., stirring for 45 min; removal of volatiles in vac., as oil; monitoring by NMR; extn. with hexanes; filtration, removal of solvent of filtrate; vac. distn. twice at 120-130°C/0.2 Torr;
in tetrahydrofuran (Ar); using Schlenk techniques; charging of glass reactor with soln. of B(C6F5)3 (1 equiv.) in THF; addn. of Ti(OCHMe2)4 (1 equiv.) at ambient temp., stirring for 90 min;
