反式-2,4-已二烯-1-醇合成路线 （共 54 条）
反应条件
oxygen in acetic acid T=60°C; 5 h; Title compound not separated from byproducts.;
参考文献
New Journal of Chemistry, , vol. 27, # 2 p. 324 - 328
反应条件
1: diethyl ether; HCl / -5 °C 2: aqueous NaHCO3 3: diethyl ether; HCl / -5 °C 4: glacial acetic acid / zuletzt bei 45-50grad View Scheme
参考文献
Nasarow; Fischer
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1948 , p. 436,441
Chem.Abstr., 1949 , p. 2576
反应条件
pyridinium p-toluenesulfonate in benzene
acetalisation; Heating;
参考文献
Panda, Jagannath; Ghosh, Sarita; Ghosh, Subrata
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 22 p. 3013 - 3016
反应条件
oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium nitrite in dichloromethane; acetic acid
T=20°C; 20 h;
参考文献
Wang, Lianyue; Li, Jun; Yang, Hua; Lv, Ying; Gao, Shuang
Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 790 - 794
反应条件
oxygen in acetic acid
T=60°C; 5 h; Title compound not separated from byproducts.;
参考文献
Choi, Kwang-Min; Akita, Tomoki; Mizugaki, Tomoo; Ebitani, Kohki; Kaneda, Kiyotomi
New Journal of Chemistry, 2003 , vol. 27, # 2 p. 324 - 328
反应条件
1: pyridine; diethyl ether; thionyl chloride / 0 °C
2: und Kochen des Reaktionsprodukts mit alkoh.KOH
View Scheme
参考文献
Reichstein; Trivelli
Helvetica Chimica Acta, 1932 , vol. 15, p. 256
Helvetica Chimica Acta, 1933 , vol. 16, p. 972
反应条件
sodium hydride in tetrahydrofuran
0 deg C to rt;
参考文献
Gilbertson, Scott R.; Hoge, Garrett S.; Genov, Daniel G.
Journal of Organic Chemistry, 1998 , vol. 63, # 26 p. 10077 - 10080
反应条件
1: 60 percent / pyridine, PBr3 / hexane / 2 h / 0 °C
2: 64 percent / BuLi / 1.) THF, hexane, -20 deg C, 1 h, 2.) THF, 2 h; r.t., 15 h
3: 2 percent / H2 / Cr(CO)6 / methanol / 2 h / 190 - 200 °C / 36775.4 Torr
View Scheme
参考文献
Furuhata, Akimichi; Onishi, Ken; Fujita, Akira; Kogami, Kunio
Agricultural and Biological Chemistry, 1982 , vol. 46, # 7 p. 1757 - 1760
反应条件
hydrogen; (methyl benzoate)Cr(CO)6 in methanol
T=190 - 200°C; P=36775.4 Torr; 2 h;
参考文献
Furuhata, Akimichi; Onishi, Ken; Fujita, Akira; Kogami, Kunio
Agricultural and Biological Chemistry, 1982 , vol. 46, # 7 p. 1757 - 1760
参考文献
Reichstein; Ammann; Trivelli
Helvetica Chimica Acta, 1932 , vol. 15, p. 264
