in tetrahydrofuran; diethyl ether addn. of Me3SnK in THF/ether to a soln. of 2-bromooctane in THF/ether at 0°C under Ar; quenching after 1 h with a large excess H2O2, extg. (pentane), washing of extracts (H2O), drying (Na2SO4), GLPC;
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Mkrtchyan, A. M.; Gasparyan, S. M.; Sarkisyan, V. Yu.; Martirosyan, Z. A.; Voskanyan, E. S.
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triethylsilane; t-BuON=NOt-Bu in hexane 1 h; Heatingalso with t-dodecanethiol (catalyst); other dialkyl sulphides; Mechanism;
参考文献
Cole, Stephen J.; Kirwan, J. Nicholas; Roberts, Brian P.; Willis, Colin R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 1 p. 103 - 112
Ru3(CO)12*3PPh3; hydrogen in 1,4-dioxane; benzene T=70°C; P=760 Torr; other ligands (instead of PPh3), var. ligand/Ru3(CO)12 ratio, other solvents; Product distribution;
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