zinc dihydride; Zr catalyst in toluene T=80°C; 3 h; catalyzed hydrozincation of olefins by ZnCl2; Product distribution;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 32, # 5 p. 1080 - 1081
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 5 p. 1195 - 1197
NiCRA-bpy (2/2/1/2) in ethylene glycol dimethyl ether T=65°C; 18 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 55, # 25 p. 6194 - 6198
in hexane; cyclohexane LiH prepared from TMTH (2.00 mmol) and LDA (1.00 mmol, 1.6 M soln. in cyclohexane) in hexane for 3 h at room temp. under Ar, 1-bromooctane (1.00 mmol) added, stirred for 3 h at room temp.; GC analysis;
