in diethyl ether; cyclohexane to 1-bromooctane (1 mmol) and TMTH (1 mmol) in Et2O at 0°C added LDA (1 mmol, in cyclohexane) under Ar, stirred for 20 min, quenched; analyzed by GLPC;
palladium diacetate in tetrahydrofuran; benzene byproducts: octene (mixt. of isomers); To the soln. of Pd(OAc)2 in benzene is added a soln. of trioctylborane in THF, mixt. is refluxed for 30 min.; GLC analysis is rect. mixt. using internal standard cyclooctane.;
参考文献
Journal of the American Chemical Society, , vol. 111, # 1 p. 314 - 321
