tert.-butylhydroperoxide; Mn(2+)*C6H10(NCH3CH2C5H4N)2*2CF3SO3(1-)=Mn(C6H10(NCH3CH2C5H4N)2)(CF3SO3)2 in acetonitrile
T=0°C; 3.5 h; optical yield given as percent eeenantioselective reaction;
参考文献
Ottenbacher, Roman V.; Bryliakov, Konstantin P.; Talsi, Evgenii P.
Inorganic Chemistry, 2010 , vol. 49, # 18 p. 8620 - 8628
carbon monoxide; bis(diphenylphosphino)butane; tetrakis(triphenylphosphine) palladium(0) in toluene
T=150°C; P=62320 Torr; 72 h; effect of different catalysts and additives; Product distributionMechanism;
参考文献
Lin, Ivan J. B.; Alper, Howard
Journal of the Chemical Society, Chemical Communications, 1989 , p. 248 - 249
Armstrong, Susan K.; Cross, Ronald J.; Farrugia, Louis J.; Nichols, David A.; Perry, Alexis
European Journal of Inorganic Chemistry, 2002 , # 1 p. 141 - 151
water in acetonitrile
3 h; Ambient temperature; Yields of byproduct given;
参考文献
Yoshida, Masato; Sasage, Shuichi; Kawamura, Kyoko; Suzuki, Takashi; Kamigata, Nobumasa
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 2 p. 416 - 422