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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1-辛烯
合成路线
（共 2108 条）
111-66-0
1-辛烯
+
201230-82-2
→
反应条件
124-19-6
壬醛
+
18824-63-0
1,1-二甲氧基壬烷
+
49642-49-1
+
85197-93-9
反应条件
methanol; dicarbonylacetylacetonato rhodium (I); C25H27N2O3P; hydrogen; bis-(trifluoromethylsulphonyl)amine T=80°C; P=15001.5 Torr; 2 h; Schlenk techniqueAutoclaveIonic liquid;
参考文献
Jin, Xin; Zhao, Kun; Kong, Fangfang; Cui, Feifei; Yang, Daoxing
Catalysis Letters, 2013 , vol. 143, # 8 p. 839 - 843
111-66-0
1-辛烯
+
201230-82-2
→
反应条件
124-19-6
壬醛
+
111-65-9
正辛烷
+
111-67-1
2-辛烯
+
818-81-5
2-甲基-1-辛醇
+
49642-49-1
+
143-08-8
正壬醇
反应条件
potassium hydroxide; water; Rh6(CO)12 in 2-ethoxy-ethanol T=80°C; P=3677.5 Torr; 5 h; Product distribution;
参考文献
Chemistry Letters, , p. 1763 - 1766
111-66-0
1-辛烯
+
201230-82-2
→
反应条件
124-19-6
壬醛
+
111-65-9
正辛烷
+
111-67-1
2-辛烯
+
27649-40-7
+
49642-49-1
+
140238-46-6
反应条件
hydrogen; dicobalt octacarbonyl; tributylphosphine in methanol T=85°C; P=60004.8 Torr; Irradiationfurther catalysts: Co2(CO)8, Co2(CO)6/PBu3, Co(OAc)2, Co(OAc)2/PBu3; Product distributionKineticsQuantum yield;
参考文献
Mirbach, Manfred J.; Topalsavoglou, Nikolaos; Phu, Tuyet Nhu; Mirbach, Marlis F.; Saus, Alfons
Chemische Berichte, 1983 , vol. 116, # 4 p. 1422 - 1440
67-56-1
甲醇
+
111-66-0
1-辛烯
+
201230-82-2
→
反应条件
124-19-6
壬醛
+
111-65-9
正辛烷
+
18824-63-0
1,1-二甲氧基壬烷
+
49642-49-1
+
85197-93-9
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
75-85-4
2-甲基-2-丁醇
+
111-66-0
1-辛烯
+
201230-82-2
→
反应条件
124-19-6
壬醛
+
111-65-9
正辛烷
+
49642-49-1
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
64-17-5
乙醇
+
111-66-0
1-辛烯
+
201230-82-2
→
反应条件
124-19-6
壬醛
+
111-65-9
正辛烷
+
54815-13-3
壬醛二乙缩醛
+
49642-49-1
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
111-66-0
1-辛烯
+
201230-82-2
+
107-21-1
乙二醇
→
反应条件
5432-30-4
2-辛基-1,3-二氧戊环
+
124-19-6
壬醛
+
111-65-9
正辛烷
+
49642-49-1
+
31637-03-3
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
111-66-0
1-辛烯
+
201230-82-2
+
67-63-0
异丙醇
→
反应条件
124-19-6
壬醛
+
111-65-9
正辛烷
+
49642-49-1
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
111-66-0
1-辛烯
+
201230-82-2
+
504-63-2
1,3-丙二醇
→
反应条件
124-19-6
壬醛
+
55169-85-2
+
17357-15-2
+
111-65-9
正辛烷
+
49642-49-1
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene T=110°C; P=22502.3 Torr; 1.5 h; Autoclave; regioselective reaction;
参考文献
Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677
111-66-0
1-辛烯
+
201230-82-2
+
1333-74-0
氢气
→
反应条件
124-19-6
壬醛
+
49642-49-1
反应条件
[rhodium(I)(carbonyl)2(acetylacetonate)] in toluene T=90°C; P=15001.5 Torr; 4.5 h; Autoclave; Catalytic behaviorKinetics;
参考文献
Cardozo, Andres F.; Manoury, Eric; Julcour, Carine; Blanco, Jean-Francois; Delmas, Henri; Gayet, Florence; Poli, Rinaldo
Dalton Transactions, 2013 , vol. 42, # 25 p. 9148 - 9156
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