in water
aq. soln. of sodium tetrachloroaurate was added to a stirred aq. soln. of the ligand; the ppt. was washed with water and ethanol, then dried;
参考文献
McNeillie, Alistair; Brown, Donald H.; Smith, Ewen W.; Gibson, Martin; Watson, Lewis
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1980 , p. 767 - 770
1: 85 percent / caustic soda / 5.67 h / Heating
2: 75 percent / 120 °C
View Scheme
参考文献
Krivonogov, V. P.; Shayakhmetova, R. M.; Dronov, V. I.; Enikeev, R. S.; Nikitin, Yu. E.; et al.
J. Appl. Chem. USSR (Engl. Transl.), 1981 , vol. <2> 54, # 11 p. 2505 - 2510,2210 - 2215
1: n-octanethiol With sodium salt of phosphorous acid in N,N-dimethyl-formamide
0.25 h;
2: monobromotrifluoromethane With hydroxymethanesulfinic acid sodium salt in N,N-dimethyl-formamide
T=20°C; P=3375.27 Torr; 8 h; Title compound not separated from byproducts;
参考文献
Magnier, Emmanuel; Wakselman, Claude
Synthesis, 2003 , # 4 p. 565 - 569
