hydrogenchloride in deuterated toluene Under protective gas, thermolysis in toluene at 82°C for 48 h followed by hydrolysis with HCl.; Centrifugation, seperation, evapn. of org. layer, GC/MS.;

With  hydrogenchloride in  deuterated toluene  Kinetics;  Soln. of Cp2Zr(p-CH3C6H4)(CH(SC6H5)(Si(CH3)3)) is thermolyzed in sealed NMR-tube at 82°C under protective gas, after 12 h tube is broken, addn. of conc. HCl.; Monitored by (1)H-NMR, mixing of layers, sepg. of org. layer, vac. distn., NMR and GC/MS.;