rhodium in neat (no solvent) gas mixt. (13CO:14NO = 1:1, P = 7.5E-5 Torr) introduced in react. chamber with Rh(110) catalyst (300-900 K); LEED, XPS, QMS;
参考文献
Journal of Physical Chemistry B, , vol. 108, # 38 p. 14232 - 14243
catalyst: Pd/Al2O3 in water; acetic acid PVMo-contg. compd. (5E-6 mol) was dissolved in 9:1 AcOH/H2O; addn. of CO(2 bar) at 90°C for 5 h in the presence of 5percent Pd/Al2O3; (13)C NMR studies at 125 ppm;
