in water; acetic acid; ethyl acetate byproducts: (13)CH4; High Pressure; IrI3/IrI4, (PtI2(CO))2 (Pt/Ir=1/4) in CH3COOH (64 wtpercent), CH3COOCH3 (20 wtpercent), H2O (6 wtpercent), (13)CH3I (10 wtpercent), pressured under 30 bar of (12)CO/(13)CO, heated to 86°C; not sepd., detected by spectra;
in neat (no solvent) byproducts: (13)CO; High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC;
参考文献
Kudo, Kiyoshi; Ikoma, Futoshi; Mori, Sadayuki; Komatsu, Koichi; Sugita, Nobuyuki
Journal of the Chemical Society, Chemical Communications, 1995 , # 6 p. 633 - 634
in tetrahydrofuran soln. of the W-compound was treated with gasous (13)CO2 at -78°C, warmed to 25°C; solvent removed (vac.), extd. (diethyl ether), ether removed (vac.); IR, MAS;
参考文献
Maher, John M.; Cooper, N. John
Journal of the American Chemical Society, 1980 , vol. 102, p. 7604 - 7606
in neat (no solvent) introducing (13)CO2 into glass bulb contg. H2(18)O, keeping for at leasta day at room temp.; release of CO2 isotopomer by slowly warming CO2/H2O mixture from liquid nitrogen temp.;
参考文献
Xu, Yunjie; Jaeger, Wolfgang
Journal of Molecular Structure, 2001 , vol. 599, p. 211 - 217
