(HOCH2CH2N)3N; [Ru(2,2′-bipyridine)3]2+; Co(2,2’-bipyridine)3Cl2 in N,N-dimethyl-formamide Irradiation (UV/VIS); 30 ° C, irradn. for 15 h, DMF/amine 2:1; gas analysed by GC;
参考文献
Ziessel, Raymond; Hawecker, Jeannot; Lehn, Jean-Marie
Helvetica Chimica Acta, 1986 , vol. 69, p. 1065 - 1084
catalyst: K2CO3/Norit RX extra in gas Kinetics; (13)CO2/(12)CO/He feed flow, 950 K, pressure of CO or CO2: 7-67 kPa, other reactand pressure keeping constant;
参考文献
Cerfontain, M. B.; Meijer, R.; Kapteijn, F.; Moulijn, J. A.
Journal of Catalysis, 1987 , vol. 107, p. 173 - 180
cis-{Os(2,2'-bipyridine)2(CO)(2)H} hexafluorophosphate in water; acetonitrile Kinetics; Electrolysis; Sustained electrolysis of solns. of complex in CO2-satd. CH3CN with added H2O at potentials of -1.4 to -1.6 V at a Pt mesh working electrode.;
参考文献
Bruce, Mitchell R. M.; Megehee, Elise; Sullivan, B. Patrick; Thorp, Holden; O'Toole, Terrence R.; et al.
Organometallics, 1988 , vol. 7, p. 238 - 240
→
反应条件
in THF-d8 (tetrahydrofuran-d8) introducing (13)CO2 to soln. of copper compd. in THF-d8 at -80°C in NMR tube, gradual warming to -40°C for 30 min; NMR detection;
参考文献
Laitar, David S.; Mueller, Peter; Sadighi, Joseph P.
Journal of the American Chemical Society, 2005 , vol. 127, # 49 p. 17196 - 17197
→
反应条件
in neat (no solvent) Irradiation (UV/VIS); a soln. of complex photolysed, reacted with (13)CO2, monitored by NMR, FTIR and GC; not isolated;
参考文献
Hayashi, Yukiko; Kita, Shouichi; Brunschwig, Bruce S.; Fujita, Etsuko
Journal of the American Chemical Society, 2003 , vol. 125, # 39 p. 11976 - 11987
