3,3-二甲基-1,4-戊二烯合成路线 （共 16 条）
反应条件
{(C8H14)2RhCl2}2; tri-cyclo-hexyl-phosphine in toluene T=170°C; 4 h;
参考文献
Lee, Dae-Yon; Kim, In-Jung; Jun, Chul-Ho
Angewandte Chemie - International Edition, 2002 , vol. 41, # 16 p. 3031 - 3033
参考文献
Merck and Co., Inc.
Patent: US4262010 A1, 1981 ;
反应条件
sodium hydroxide; tetraethylene glycol
T=180°C;
参考文献
Eilbracht, Peter; Acker, Michael; Totzauer, Walter
Chemische Berichte, 1983 , vol. 116, # 1 p. 238 - 242
参考文献
Tagge, Christopher D.; Simpson, Robert D.; Bergman, Robert G.; Hosteller, Michael J.; Girolami, Gregory S.; Nuzzo, Ralph G.
Journal of the American Chemical Society, 1996 , vol. 118, # 11 p. 2634 - 2643
反应条件
1: 77 percent / 47percent aq. HBr / H2SO4 / 20 h / Heating
2: 50 percent / NaOH, tetraethyleneglycol / 180 °C
View Scheme
参考文献
Eilbracht, Peter; Acker, Michael; Totzauer, Walter
Chemische Berichte, 1983 , vol. 116, # 1 p. 238 - 242
反应条件
1: 95 percent / LiAlH4 / diethyl ether; tetrahydrofuran / 1) 2 h, reflux, 2) 12 h, r.t.
2: 77 percent / 47percent aq. HBr / H2SO4 / 20 h / Heating
3: 50 percent / NaOH, tetraethyleneglycol / 180 °C
View Scheme
参考文献
Eilbracht, Peter; Acker, Michael; Totzauer, Walter
Chemische Berichte, 1983 , vol. 116, # 1 p. 238 - 242
反应条件
1: LiAlH4 / diethyl ether / Heating
2: Py
3: LiBr / acetone / Heating
4: NaI, 2-methyl-quinoline / 2 h / 90 °C
View Scheme
参考文献
Miller,R.G. et al.
Journal of the American Chemical Society, 1974 , vol. 96, p. 4211 - 4220
反应条件
T=350°C; P=129287 Torr;
参考文献
Cywinski,N.F.
Journal of Organic Chemistry, 1965 , vol. 30, p. 361 - 364
反应条件
2-Methyl quinoline; sodium iodide
参考文献
Ciola; Burwell
Journal of Organic Chemistry, 1958 , vol. 23, p. 1063
参考文献
Lukes,R.; Hofman,J.
Chemische Berichte, 1960 , vol. 93, p. 2556 - 2561
