potassium tert-butylate in N,N-dimethyl-formamide
T=90°C; 72 h;
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 3 steps 1: 73 percent / m-chloroperbenzoic acid / ethanol / 18 h / 4 °C2: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C3: 85 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 2 steps 1: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C2: 85 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 2 steps 1: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C2: 85 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 2 steps 1: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C2: 85 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 2 steps 1: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C2: 85 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 3 steps 1: 75 percent / sodium metaperiodate / methanol; H2O / 18 h / 0 °C2: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C3: 33 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 3 steps 1: 75 percent / sodium metaperiodate / methanol; H2O / 18 h / 0 °C2: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C3: 57 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
Multi-step reaction with 3 steps 1: 75 percent / sodium metaperiodate / methanol; H2O / 18 h / 0 °C2: potassium-t-butoxide / dimethylformamide / 72 h / 37 °C3: 60 percent / bis-(4-hydroxy-5-methyl-3-t-butylphenyl)sulphide, HCl / H2O; acetonitrile / 1 h / 80 °C
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
With 3-chloro-benzenecarboperoxoic acid in ethanol T=20°C; 18 h;
参考文献
Jones, A. Stanley; McClean, Michael J.; Slater, Martin J.; Walker, Richard T. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 457 - 464
