(R)-(+)-β-香茅醇合成路线 (共 81 条)
反应条件
C28H42FeO4Si2; hydrogen; potassium carbonate in water; isopropyl alcohol T=100°C; P=22502.3 Torr; 17 h; Inert atmosphere;
参考文献
Fleischer, Steffen; Zhou, Shaolin; Junge, Kathrin; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 19 p. 5120 - 5124
Angew. Chem., 2013 , vol. 125, # 19 p. 5224 - 5228
反应条件
lithium aluminium tetrahydride
参考文献
Naoshima, Yoshinobu; Hayashi, Daijiro; Ochi, Masato
Agricultural and Biological Chemistry, 1988 , vol. 52, # 6 p. 1605 - 1606
反应条件
[Ru(p-cymene)I-(S)-binap]I; hydrogen in methanol; water T=20°C; P=73550.8 Torr; 8 h;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 17 p. 1208 - 1210
反应条件
hydrogen; Ru/(S)-BINAP in methanol T=40°C; P=75007.5 Torr; 24 h;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2006/56435 A1, 2006 ;
Location in patent: Page/Page column 23 ;
反应条件
lt;lt;(-)-2,2'-bis(diphenylphosphino)-4,4',6,6'-tetramethyl-3,3'-bibenzolt;bgt;thiophenegt;Ru(p-cumene)Igt;I; hydrogen in methanol T=25°C; P=7355.08 Torr; 88 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 61, # 18 p. 6244 - 6251
反应条件
diisobutylaluminium hydride in tetrahydrofuran T=-78°C; 1 h;
参考文献
Shull, Brian K.; Koreeda, Masato
Journal of Organic Chemistry, 1990 , vol. 55, # 7 p. 2249 - 2251
参考文献
Takasago International Corporation
Patent: US5206399 A1, 1993 ;
反应条件
hydrogen; diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) in methanol T=25°C; 5 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 16 p. 2309 - 2322
反应条件
diisobutylaluminium hydride in tetrahydrofuran T=-78°C; also with LAH;
参考文献
Shull, Brian K.; Koreeda, Masato
Journal of Organic Chemistry, 1990 , vol. 55, # 7 p. 2249 - 2251
反应条件
hydrogen; [Ru(p-cymene)I-(S)-binap]I in methanol; water T=20°C; P=76000 Torr; 8 h; Yield given. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 59, # 11 p. 3064 - 3076