(R)-(+)-β-香茅醇合成路线 (共 81 条)
反应条件
diisobutylaluminium hydride in diethyl ether; toluene T=0 - 20°C; 17 h;
参考文献
Odinokov, V. N.; Akhmetova, V. R.; Khasanov, Kh. D.; Abduvakhabov, A. A.; Sul'tanmuratova, V. R.; Tolsikov, G. A.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 6.1 p. 915 - 918
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 6 p. 1173 - 1177
反应条件
phosphate buffer; propionic acid methyl ester 96 h; Ambient temperature;
参考文献
Cambou, Bernard; Klibanov, Alexander M.
Journal of the American Chemical Society, 1984 , vol. 106, # 9 p. 2687 - 2692
反应条件
sodium hydroxide in ethanol T=20 - 75°C; Decarboxylation; P=0.5 Torr; 4 h;
参考文献
Journal of Chemical Ecology, , vol. 24, # 8 p. 1347 - 1353
反应条件
{[(S)-2,2'-di((p-tolyl)2P)-1,1'-binaphthyl]RuCl2}2*NEt3; hydrogen in methanol T=19.9°C; P=3750.3 Torr; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 117, # 50 p. 12647 - 12648
反应条件
hydrogen; lt;(+)-CyBINAPgt;-RhN in benzene P=15200 Torr; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Chemistry Letters, , p. 1007 - 1008
反应条件
diisobutylaluminium hydride in tetrahydrofuran; toluene T=-78°C; 0.5 h;
参考文献
Journal of the Chinese Chemical Society (Taipei, Taiwan), , vol. 42, # 4 p. 709 - 712
反应条件
glucose-6-phosphate dehydrogenase; glucose-6-phosphate; Saccharomyces pastorianus old yellow enzyme W116F; NADP T=20°C; 24 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 131, p. 3271 - 3280
反应条件
glucose-6-phosphate dehydrogenase; glucose-6-phosphate; Saccharomyces pastorianus old yellow enzyme wild type; NADP T=20°C; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 131, p. 3271 - 3280
反应条件
1: HCl gas / 24 h / 0 °C 2: 79 percent / 1 M DIBAL / tetrahydrofuran / 1 h / -78 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 55, # 7 p. 2249 - 2251