Mastagli
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1937 , vol. 204, p. 1656
Annales de Chimie (Cachan, France), 1938 , vol. <11> 10, p. 281,369
Mastagli
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1937 , vol. 204, p. 1656
Annales de Chimie (Cachan, France), 1938 , vol. <11> 10, p. 281,369
1: NaNH2; ethanol; diethyl ether / Acetylierung des erhaltenen Gemisches von 3-Hydroxy-tridecanal-(1) und 3-Formyl-dodecanol-(2) und Erhitzen des Reaktionsprodukts mit Kupferpulver auf 150grad
2: platinum; ethanol / Hydrogenation
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参考文献
Stoll
Helvetica Chimica Acta, 1947 , vol. 30, p. 997
1: 1.) n-BuLi / 1.) from -78 deg C to 25 deg C, 30 min, 2.) from -78 deg C to 25 deg C, 1 h
2: 90 percent / Bu4NF / tetrahydrofuran / 2 h / 25 °C
View Scheme
参考文献
Cravatt, Benjamin F.; Lerner, Richard A.; Boger, Dale L.
Journal of the American Chemical Society, 1996 , vol. 118, # 3 p. 580 - 590
1: dimethyl lt;1-(methoxycarbonyl)ethylgt;phosphonate With sodium hydride in tetrahydrofuran; mineral oil
T=0 - 40°C; Horner-Wadsworth-Emmons olefination;
2: pentylpentylketone in tetrahydrofuran; mineral oil
Horner-Wadsworth-Emmons olefination; 24 h; Reflux;
3: With platinum(IV) oxide; hydrogen in methanol
参考文献
Nawrath, Thorben; Gerth, Klaus; Mueller, Rolf; Schulz, Stefan
Chemistry and Biodiversity, 2010 , vol. 7, # 9 p. 2228 - 2253
