反应条件
1: 1.) CoCl2*6H2O, dimethylglyoxime, pyridine, 50percent aq.NaOH, NaBH4 / 1.) MeOH, THF, 0 deg C, 3 h; room temperature, 30 min, 2.) CH3CN, irradiation, 10 h
2: 98 percent / m-CPBA, phosphate buffer / CH2Cl2 / 2.5 h / 0 °C
View Scheme
参考文献
Branchaud, Bruce P.; Slade, Rachel M.
Tetrahedron Letters, 1994 , vol. 35, # 24 p. 4071 - 4072