1: 5-iodo-1-methylpyrazole With tert.-butyl lithium in tetrahydrofuran; pentane
T=-78°C; 2 h;
2: With indium(III) chloride in tetrahydrofuran; pentane
T=-78 - 20°C;
3: 3-iodo-pyridine With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; pentane
Heating; Further stages.;
参考文献
Font-Sanchis, Enrique; Cespedes-Guirao, F. Javier; Sastre-Santos, Angela; Fernandez-Lazaro, Fernando
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3589 - 3591
sodium azide; C39H32Cl2OP2Pd*CH2Cl2 in tetrahydrofuran; hexane; water
T=20°C; Heck Reaction; P=760.051 Torr;
参考文献
Miloserdov, Fedor M.; McMullin, Claire L.; Belmonte, Marta Martinez; Benet-Buchholz, Jordi; Bakhmutov, Vladimir I.; Macgregor, Stuart A.; Grushin, Vladimir V.
Organometallics, 2014 , vol. 33, # 3 p. 736 - 752