(2R)-2-环氧乙烷乙酸乙酯合成路线 (共 5 条)
反应条件
Jacobsen's (R,R)-(salen)Co(III) catalyst; air; acetic acid in tetrahydrofuran T=0 - 20°C; 16 h;
参考文献
Schaus, Scott E.; Brandes, Bridget D.; Larrow, Jay F.; Tokunaga, Makoto; Hansen, Karl B.; Gould, Alexandra E.; Furrow, Michael E.; Jacobsen, Eric N.
Journal of the American Chemical Society, 2002 , vol. 124, # 7 p. 1307 - 1315
反应条件
Jacobsen's (R,R)-(salen)Co(III) catalyst; air; acetic acid in tetrahydrofuran T=0 - 20°C;
参考文献
Schaus, Scott E.; Brandes, Bridget D.; Larrow, Jay F.; Tokunaga, Makoto; Hansen, Karl B.; Gould, Alexandra E.; Furrow, Michael E.; Jacobsen, Eric N.
Journal of the American Chemical Society, 2002 , vol. 124, # 7 p. 1307 - 1315
反应条件
(R,R)-Salen-Co; acetic acid in water
参考文献
Shen, Ruichao; Lin, Cheng Ting; Bowman, Emma Jean; Bowman, Barry J.; Porco Jr., John A.
Journal of the American Chemical Society, 2003 , vol. 125, # 26 p. 7889 - 7901
反应条件
1: 100 percent / m-CPBA / CH2Cl2 / 20 °C 2: 30 percent / (R,R)-salen-Co; AcOH / H2O View Scheme
参考文献
Shen, Ruichao; Lin, Cheng Ting; Bowman, Emma Jean; Bowman, Barry J.; Porco Jr., John A.
Journal of the American Chemical Society, 2003 , vol. 125, # 26 p. 7889 - 7901
反应条件
FAS; mercury(II) dithiocyanate in ethanol T=30°C; pH=7.5; Enzymatic reaction; Kinetics;
参考文献
Schallmey, Marcus; Floor, Robert J.; Hauer, Bernhard; Breuer, Michael; Jekel, Peter A.; Wijma, Hein J.; Dijkstra, Bauke W.; Janssen, Dick B.
ChemBioChem, 2013 , vol. 14, # 7 p. 870 - 881