2-甲基-2-环己烯-1-酮合成路线 （共 131 条）
反应条件
2-hydroxyethyl phenyl sulfide; caesium carbonate in acetonitrile; tert-butyl alcohol
T=80°C; Baylis-Hillman Reaction; 24 h;
参考文献
Gradillas, Ana; Belmonte, Efres; Da Silva, Rondes Ferreira; Perez-Castells, Javier
European Journal of Organic Chemistry, 2014 , vol. 2014, # 9 p. 1935 - 1941
反应条件
titanium(IV) isopropylate; 4 A molecular sieve; oxygen; 5,15,10,20-tetraphenylporphyrin in dichloromethane
T=-10 - -5°C; 6 h; Irradiation;
参考文献
Adam, Waldemar; Richter, Markus J.
Journal of Organic Chemistry, 1994 , vol. 59, # 12 p. 3341 - 3346
反应条件
diethyl allyl phosphate; sodium carbonate; palladium diacetate in tetrahydrofuran
T=86°C; 21 h; Yield given. Yields of byproduct given;
参考文献
Shvo, Youval; Arisha, Anan Haj Ichia
Journal of Organic Chemistry, 1998 , vol. 63, # 16 p. 5640 - 5642
反应条件
1: With trimethylsilylating agent
2: With 4-methoxypyridine-N-oxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in dichloromethane; dimethyl sulfoxide
T=20°C; 1 h; Title compound not separated from byproducts;
参考文献
Nicolaou; Gray, David L. F.; Montagnon, Tamsyn; Harrison, Scott T.
Angewandte Chemie - International Edition, 2002 , vol. 41, # 6 p. 996 - 1000
反应条件
1-methyl-pyrrolidin-2-one; copper(l) iodide; bis(benzonitrile)palladium(II) dichloride; triphenyl-arsane
T=80°C; 40 h;
参考文献
Bellina, Fabio; Carpita, Adriano; Ciucci, Donatella; De Santis, Massimo; Rossi, Renzo
Tetrahedron, 1993 , vol. 49, # 21 p. 4677 - 4698
反应条件
diallyl carbonate; palladium diacetate; 1,2-bis-(diphenylphosphino)ethane in acetonitrile
Heating;
参考文献
Minami, Ichiro; Takahashi, Kazuhiko; Shimizu, Isao; Kimura, Tsuneo; Tsuji, Jiro
Tetrahedron, 1986 , vol. 42, # 11 p. 2971 - 2978
反应条件
methyl allyl carbonate; palladium diacetate; tri-n-butyltin methoxide; 1,2-bis-(diphenylphosphino)ethane in acetonitrile
10 h; Heating;
参考文献
Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao
Tetrahedron Letters, 1983 , vol. 24, # 50 p. 5639 - 5640
反应条件
oxygen; iron(III) chloride
T=60°C; P=760 Torr;
参考文献
Ito, Satoru; Aihara, Kazuhisa; Matsumoto, Masakatsu
Tetrahedron Letters, 1984 , vol. 25, # 35 p. 3891 - 3894
反应条件
1: With pentacarbonyliron(0) in tetrahydrofuran
1 h; IrradiationInert atmosphere;
2: With methanesulfonyl chloride; triethylamine in dichloromethane
T=20°C; 24 h; Inert atmosphere;
参考文献
Mac, Dinh Hung; Samineni, Ramesh; Petrignet, Julien; Srihari, Pabbaraja; Chandrasekhar, Srivari; Yadav, Jhillu Singh; Gree, Rene
Chemical Communications, 2009 , # 31 p. 4717 - 4719
反应条件
oxygen; iron(III) chloride
T=60°C; P=760 Torr;
参考文献
Ito, Satoru; Aihara, Kazuhisa; Matsumoto, Masakatsu
Tetrahedron Letters, 1984 , vol. 25, # 35 p. 3891 - 3894
