2-甲基-2-环己烯-1-酮合成路线 （共 131 条）
反应条件
1: With diphenylphosphoranyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene in diethyl ether
T=0 - 20°C; 1 h; Inert atmosphere;
2: With selenium(IV) oxide in dichloromethane
T=20°C; 48 h; Inert atmosphere;
参考文献
Hanessian, Stephen; Szychowski, Janek; Pablo Maianti
Organic Letters, 2009 , vol. 11, # 2 p. 429 - 432
反应条件
hydrogen; oxygen in methanol; acetonitrile
T=59.84°C; P=760.051 Torr; 6 h;
参考文献
Okada, Shusuke; Fujiwara, Kensei; Kamegawa, Takashi; Mori, Kohsuke; Yamashita, Hiromi
Bulletin of the Chemical Society of Japan, 2012 , vol. 85, # 9 p. 1057 - 1059,3
反应条件
sodium periodate in methanol; water
T=40°C; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Toshimitsu, Akio; Owada, Hiroto; Terao, Keiji; Uemura, Sakae; Okano, Masaya
Journal of Organic Chemistry, 1984 , vol. 49, # 20 p. 3796 - 3800
反应条件
palladium diacetate; 1,2-bis-(diphenylphosphino)ethane in acetonitrile
4 h; Heating; Yields of byproduct given;
参考文献
Minami, Ichiro; Nisar, Mohammad; Yuhara, Masami; Shimizu, Isao; Tsuji, Jiro
Synthesis, 1987 , # 11 p. 992 - 998
反应条件
2-hydroxy-1,3-isoindolinedione in pyridine; acetonitrile
electrochemical oxidation; Mechanism;
参考文献
Masui, Masaichiro; Hosomi, Katsuko; Tsuchida, Keiichi; Ozaki, Shigeko
Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 11 p. 4798 - 4802
反应条件
potassium carbonate in acetone
Heating;
参考文献
Baraldi, Pier Giovanni; Barco, Achille; Benetti, Simonetta; Pollini, Gian Piero; Zanirato, Vinicio
Tetrahedron Letters, 1984 , vol. 25, # 38 p. 4291 - 4294
反应条件
D-glucose; Yamadazyma farinosa IFO 10896 in phosphate buffer
T=30°C; pH=6.5; 0.5 h; Further byproducts. Title compound not separated from byproducts.;
参考文献
Matsumoto, Kazutsugu; Kawabata, Yoichi; Okada, Satoshi; Takahashi, Jun; Hashimoto, Key; Nagai, Yuto; Tatsuta, Junichi; Hatanaka, Minoru
Chemistry Letters, 2007 , vol. 36, # 12 p. 1428 - 1429
反应条件
1: 77 percent / K2CO3 / acetone / 5 h / Heating
2: 72 percent / Pd(OAc)2, dppe / acetonitrile / 4 h / Heating
View Scheme
参考文献
Minami, Ichiro; Nisar, Mohammad; Yuhara, Masami; Shimizu, Isao; Tsuji, Jiro
Synthesis, 1987 , # 11 p. 992 - 998
反应条件
1: 72 percent / 24 h / Heating
2: 77 percent / K2CO3 / acetone / 5 h / Heating
3: 72 percent / Pd(OAc)2, dppe / acetonitrile / 4 h / Heating
View Scheme
参考文献
Minami, Ichiro; Nisar, Mohammad; Yuhara, Masami; Shimizu, Isao; Tsuji, Jiro
Synthesis, 1987 , # 11 p. 992 - 998
反应条件
hydrogenchloride
6 h; Heating;
参考文献
Marchetti, Mauro
Journal of Heterocyclic Chemistry, 1988 , vol. 25, p. 1761 - 1765
