1: oct-1-ene With 9-bora-bicyclo[3.3.1]nonane in tetrahydrofuran T=20°C; 15 h; 2: With sodium hydroxide in tetrahydrofuran 3: 4-bromo-benzaldehyde With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran Inert atmosphereReflux;
参考文献
UNIVERSITY OF VIRGINIA PATENT FOUNDATION
Patent: WO2009/146112 A1, 2009 ;
Location in patent: Page/Page column 31; 32 ;
WO 2009/146112 A1
1: 4-bromo-1-iodobenzene With copper; zinc in N,N-dimethyl-formamide T=125°C; 0.25 h; 2: 4-bromo-benzaldehyde With bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=120°C; Negishi cross-coupling reaction; 0.0833333 h; Further stages.;
