3,5-二甲基-2-环己烯-1-酮合成路线 （共 86 条）
反应条件
oxygen; molybdovanadophosphate on active carbon in toluene T=100°C; P=760 Torr; 20 h; Yield given. Yields of byproduct given;
参考文献
Hanyu, Atsushi; Sakurai, Yasunori; Fujibayashi, Shinya; Sakaguchi, Satoshi; Ishii, Yasutaka
Tetrahedron Letters, 1997 , vol. 38, # 32 p. 5659 - 5662
反应条件
1.1: tert.-butyl lithium / tetrahydrofuran; pentane / -65 - -20 °C / Inert atmosphere 1.2: 2 h / -35 - 20 °C / Inert atmosphere 2.1: hydrogenchloride / methanol; water / 0.08 h 3.1: sulfuric acid; acetic acid / 0.5 h / 75 °C View Scheme
参考文献
Gehring, Andrep.; Bracher, Franz
Synthesis (Germany), 2012 , vol. 44, # 15 p. 2441 - 2447
反应条件
hydrogen; ethylmethylphenylphosphine; tert-butyl alcohol; [{(Ph3P)CuH}6] in benzene T=20°C; Catalytic hydrogenation; P=25857.4 Torr; 20 h;
参考文献
Chen, Jian-Xin; Daeuble, John F.; Stryker, Jeffrey M.
Tetrahedron, 2000 , vol. 56, # 18 p. 2789 - 2798
反应条件
hydrogen T=200°C; P=75 - 80 Torr; beim Leiten ueber Nickel;
参考文献
Knoevenagel
Justus Liebigs Annalen der Chemie, 1896 , vol. 289, p. 143
Justus Liebigs Annalen der Chemie, 1897 , vol. 297, p. 119,160, 175
反应条件
sodium tetrahydroborate; SmCpCl2(THF)3 in methanol 6 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Komiya, Sanshiro; Tsutsumi, Osamu
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3423 - 3424
反应条件
T=200°C; P=75 - 80 Torr;
参考文献
Zelinsky
Chemische Berichte, 1911 , vol. 44, p. 2779
参考文献
Canadian Journal of Chemistry, , vol. 58, p. 1639 - 1644
参考文献
Canadian Journal of Chemistry, , vol. 58, p. 1639 - 1644
反应条件
1: Methyltriphenylphosphonium bromide With n-butyllithium in diethyl ether; hexane T=0 - 20°C; 3 h; Inert atmosphere; 2: 3,5-dimethyl-cyclohex-2-en-1-one in diethyl ether; hexane 12 h; Inert atmosphere; 3: With 10 Pd/C in ethylene glycol T=190°C; 4 h; Inert atmosphereSealed tube;
参考文献
Majetich, George; Allen, Scott
Arkivoc, 2010 , vol. 2010, # 4 p. 104 - 124
反应条件
selenium(IV) oxide; acetic acid
参考文献
Dane; Schmitt
Justus Liebigs Annalen der Chemie, 1938 , vol. 536, p. 196,197,200
Justus Liebigs Annalen der Chemie, 1939 , vol. 537, p. 246,248
