反应条件
trimethylsilyl trifluoromethanesulfonate; bis(1,5-cyclooctadiene)nickel (0) in dichloromethane
(N2 or Ar); trimethylsilyl trifluoromethanesulfonate added to a soln. ofSn compd. and C6H5CH(OCH3)2 in CH2Cl2 at -78°C, stirred for 1 h at -78°C, a satd. aq. soln. of Na2CO3 added at -40°C, allo wed to warm to room temp.,; treated with solid K2CO3, a soln. of Ni complex in toluene and 1,2-heptadiene added, stirred at room temp. for 1 h, filtered, concd., chromd. (preparative GPC);
参考文献
Nakao, Yoshiaki; Shirakawa, Eiji; Tsuchimoto, Teruhisa; Hiyama, Tamejiro
Journal of Organometallic Chemistry, 2004 , vol. 689, # 23 p. 3701 - 3721
