5-(甲氧基)2-(5H)-二氧三环酮合成路线 （共 14 条）
反应条件
camphor-10-sulfonic acid T=25°C; 3 h;
参考文献
Fekner, Tomasz; Li, Xin; Lee, Marianne M.; Chan, Michael K.
Angewandte Chemie - International Edition, 2009 , vol. 48, # 9 p. 1633 - 1635
反应条件
hydrogenchloride in ethanol; water T=20°C; 2.5 h; Inert atmosphere;
参考文献
Enev, Valentin S.; Felzmann, Wolfgang; Gromov, Alexey; Marchart, Stefan; Mulzer, Johann
Chemistry - A European Journal, 2012 , vol. 18, # 31 p. 9651 - 9668
反应条件
dihydrogen peroxide; acetic acid in water 0.5 h;
参考文献
Ortuno, Rosa M.; Bigorra, Joaquim; Font, Josep
Tetrahedron, 1987 , vol. 43, # 9 p. 2199 - 2202
反应条件
hydrogen; palladium on activated charcoal in ethyl acetate T=20°C; 1 h;
参考文献
Heterocycles, , vol. 55, # 7 p. 1323 - 1328
反应条件
calcium carbonate in toluene Inert atmosphereReflux;
参考文献
Enev, Valentin S.; Felzmann, Wolfgang; Gromov, Alexey; Marchart, Stefan; Mulzer, Johann
Chemistry - A European Journal, 2012 , vol. 18, # 31 p. 9651 - 9668
反应条件
1: H2 / Lindlar catalyst / ethyl acetate / 0.42 h / Ambient temperature 2: conc. aq. HCl / methanol / 12 h / Ambient temperature View Scheme
参考文献
Synthesis, , # 10 p. 1291 - 1294
反应条件
1: 90.4 percent / p-TsOH*H2O / methanol / 12 h / Ambient temperature 2: H2 / Lindlar catalyst / ethyl acetate / 0.42 h / Ambient temperature 3: conc. aq. HCl / methanol / 12 h / Ambient temperature View Scheme
参考文献
Synthesis, , # 10 p. 1291 - 1294
反应条件
1: 50 percent / NaIO4 / aq. methanol / 20 °C 2: H2 / 10 percent Pd/C / ethyl acetate / 1 h / 20 °C View Scheme
参考文献
Heterocycles, , vol. 55, # 7 p. 1323 - 1328
反应条件
1: 85 percent / NaIO4 / aq. methanol / 1 h / 20 °C 2: H2 / 10 percent Pd/C / ethyl acetate / 1 h / 20 °C View Scheme
参考文献
Heterocycles, , vol. 55, # 7 p. 1323 - 1328
反应条件
pyridine hydrogenfluoride in tetrahydrofuran T=0°C; 16 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Angewandte Chemie, International Edition in English, , vol. 36, # 24 p. 2750 - 2752
Angewandte Chemie, , vol. 109, p. 2866 - 2868
