2,3,6,7-四甲基萘合成路线 （共 14 条）
反应条件
sulfuryl dichloride; iron(III) chloride in benzene T=60°C;
参考文献
Otsubo, Tetsuo; Sukenobe, Nobuo; Aso, Yoshio; Odura, Fumio
Chemistry Letters, 1987 , p. 315 - 316
反应条件
chloranil in toluene
12 h; Heating;
参考文献
Rosokha, Sergiy V.; Kochi, Jay K.
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9357 - 9365
参考文献
Mosby
Journal of the American Chemical Society, 1953 , vol. 75, p. 3600
反应条件
1: LiBH4 / tetrahydrofuran; methanol / -15 - 20 °C
2: 0.18 g / POCl3; pyridine / -5 - 20 °C
3: 45 percent / p-chloranil / toluene / 12 h / Heating
View Scheme
参考文献
Rosokha, Sergiy V.; Kochi, Jay K.
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9357 - 9365
参考文献
Rieke,R.D. et al.
Journal of Organic Chemistry, 1973 , vol. 38, # 7 p. 1430 - 1431
反应条件
1: 0.18 g / POCl3; pyridine / -5 - 20 °C
2: 45 percent / p-chloranil / toluene / 12 h / Heating
View Scheme
参考文献
Rosokha, Sergiy V.; Kochi, Jay K.
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9357 - 9365
反应条件
1: AcOH
2: Zn, AcOH
3: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether / Heating
4: sulfur / 235 °C
View Scheme
参考文献
Rieke,R.D. et al.
Journal of Organic Chemistry, 1973 , vol. 38, # 7 p. 1430 - 1431
反应条件
1: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether / Heating
2: sulfur / 235 °C
View Scheme
参考文献
Rieke,R.D. et al.
Journal of Organic Chemistry, 1973 , vol. 38, # 7 p. 1430 - 1431
反应条件
1: AcOH
2: Zn, AcOH
3: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether / Heating
4: sulfur / 235 °C
View Scheme
参考文献
Rieke,R.D. et al.
Journal of Organic Chemistry, 1973 , vol. 38, # 7 p. 1430 - 1431
反应条件
1: AlCl3
2: H2 / Pd-C
3: (i) SOCl2, (ii) polyphosphoric acid
4: H2 / Pd-C
5: Pd-C / 290 - 300 °C
View Scheme
参考文献
Dozen,Y.; Hatta,M.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 2842 - 2847
