2-氨基-4'-溴二苯甲酮合成路线 （共 22 条）
反应条件
sulfuric acid T=120°C; 0.25 h;
参考文献
Bioorganic and Medicinal Chemistry, , vol. 11, # 7 p. 1153 - 1160
反应条件
1: PCl5 / benzene / 0.5 h / 50 °C 2: AlCl3 / 4 h / 80 - 90 °C 3: conc. H2SO4 / 0.25 h / 120 °C View Scheme
参考文献
Bioorganic and Medicinal Chemistry, , vol. 11, # 7 p. 1153 - 1160
反应条件
1: 68.7 percent / Na2CO3 / H2O / 60 - 85 °C 2: PCl5 / benzene / 0.5 h / 50 °C 3: AlCl3 / 4 h / 80 - 90 °C 4: conc. H2SO4 / 0.25 h / 120 °C View Scheme
参考文献
Bioorganic and Medicinal Chemistry, , vol. 11, # 7 p. 1153 - 1160
反应条件
1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 0.5 h / 20 °C / Inert atmosphere 2: anhydrous iron chloride / 1,2-dichloro-ethane / 1 h / 0 °C 3: hydrogenchloride; iron / ethanol; water / 2 h / 80 °C View Scheme
参考文献
Chemical Communications, , vol. 47, # 33 p. 9513 - 9515
反应条件
1: anhydrous iron chloride / 1,2-dichloro-ethane / 1 h / 0 °C 2: hydrogenchloride; iron / ethanol; water / 2 h / 80 °C View Scheme
参考文献
Chemical Communications, , vol. 47, # 33 p. 9513 - 9515
反应条件
(i) PCl5, (ii) AlCl3, (iii) H2SO4; Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 94, p. 4952 - 4958
反应条件
sodium hydroxide; bromine
参考文献
Tetrahedron, , vol. 20, p. 803 - 821
反应条件
1: AlCl3 / 4 h / 80 - 90 °C 2: conc. H2SO4 / 0.25 h / 120 °C View Scheme
参考文献
Bioorganic and Medicinal Chemistry, , vol. 11, # 7 p. 1153 - 1160
反应条件
magnesium 1.) ether, 2.) ice-bath, 4 h; Yield given. Multistep reaction;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2077 - 2087
反应条件
bei der Beckmannschen Umlagerung;
参考文献
Justus Liebigs Annalen der Chemie, , vol. 264, p. 153
