3-甲氧基苯并[c]色烯-6-酮合成路线 （共 24 条）
反应条件
copper(I) thiophene-2-carboxylate; N,N,N',N,-tetramethylethylenediamine; caesium carbonate in water
T=300°C; P=12929 Torr; 0.166667 h; Microwave irradiation;
参考文献
Nealmongkol, Prattya; Tangdenpaisal, Kassrin; Sitthimonchai, Somkid; Ruchirawat, Somsak; Thasana, Nopporn
Tetrahedron, 2013 , vol. 69, # 44 p. 9277 - 9283
反应条件
[bis(acetoxy)iodo]benzene; potassium acetate; palladium diacetate; N-acetyl-glycine in tert-butyl alcohol
T=80°C; 12 h; Sealed tube;
参考文献
Li, Yan; Ding, Yan-Jun; Wang, Jian-Yong; Su, Yi-Ming; Wang, Xi-Sheng
Organic Letters, 2013 , vol. 15, # 11 p. 2574 - 2577
反应条件
pyridinium chlorochromate in dichloromethane
Oxidation; 1 h; Heating;
参考文献
Bowman, Russell; Mann, Emma; Parr, Jonathan
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 17 p. 2991 - 2999
反应条件
1: 1.) H2 / 1.) PtO2
2: sodium hydride / methanol
3: 17 percent / t-butyl hypoiodite / 2-methyl-propan-2-ol / 5 h / 25 °C / Irradiation
View Scheme
参考文献
Glover, Stephen A.; Golding, Stephen L.; Goosen, Andre; McCleland, Cedric W.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 842 - 848
反应条件
potassium carbonate; acetone
参考文献
Adams et al.
Journal of the American Chemical Society, 1940 , vol. 62, p. 2197,2199
参考文献
Hurtley
Journal of the Chemical Society, 1929 , p. 1872
反应条件
1.1: 15 percent / K2CO3; Br2 / CH2Cl2 / 2.5 h
2.1: NaH / tetrahydrofuran / 0.5 h / Heating
2.2: 81 percent / tetrahydrofuran / 4 h / Heating
3.1: 40 percent / Bu3SnH; azobismethylisobutyronitrile / cyclohexane / Heating
4.1: 100 percent / PCC / CH2Cl2 / 1 h / Heating
View Scheme
参考文献
Bowman, Russell; Mann, Emma; Parr, Jonathan
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 17 p. 2991 - 2999
反应条件
1: aq. H2SO4 / 2 h / Heating
2: K2CO3 / acetone / 16 h / Heating
View Scheme
参考文献
Hart, David J.; Kim, Adrienne; Krishnamurthy, Ramanarayanan; Merriman, Gregory H.; Waltos, Anne-Marie
Tetrahedron, 1992 , vol. 48, # 38 p. 8179 - 8188
反应条件
1: 1) n-butyllithium / 1) THF, hexane, -78 deg C, 0.5 h, then 0 deg C, 1.5 h, 2) THF, -78 deg C, 4 h
2: aq. H2SO4 / 2 h / Heating
3: K2CO3 / acetone / 16 h / Heating
View Scheme
参考文献
Hart, David J.; Kim, Adrienne; Krishnamurthy, Ramanarayanan; Merriman, Gregory H.; Waltos, Anne-Marie
Tetrahedron, 1992 , vol. 48, # 38 p. 8179 - 8188
反应条件
1: diluted NaOH-solution; copper sulfate
2: alkali
View Scheme
参考文献
Hurtley
Journal of the Chemical Society, 1929 , p. 1872
