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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
114332-05-7
合成路线
(共 8 条)
114332-05-7
+
67-64-1
丙酮
→
反应条件
105419-86-1
2-金刚烷-2-基-2-丙醇
反应条件
in diethyl ether T=0°C; 15 h;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976
666-52-4
氘代丙酮
+
114332-05-7
→
反应条件
281-23-2
金刚烷
+
700-57-2
2-金刚烷醇
+
29542-62-9
2,2'-联金刚烷
+
114332-09-1
反应条件
in diethyl ether T=0°C; 15 h; Further byproducts given. Yields of byproduct given;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976
666-52-4
氘代丙酮
+
114332-05-7
→
反应条件
281-23-2
金刚烷
+
700-57-2
2-金刚烷醇
+
29542-62-9
2,2'-联金刚烷
+
70334-00-8
+
114332-09-1
反应条件
in diethyl ether T=0°C; 0.25 h; without aceton-d6; several other aldehydes, ketones and acyl chlorides.; Product distribution;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976
666-52-4
氘代丙酮
+
114332-05-7
→
反应条件
281-23-2
金刚烷
+
700-57-2
2-金刚烷醇
+
29542-62-9
2,2'-联金刚烷
+
114332-09-1
反应条件
in diethyl ether T=0°C; 15 h; Further byproducts given. Yields of byproduct given;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976
666-52-4
氘代丙酮
+
114332-05-7
→
反应条件
281-23-2
金刚烷
+
700-57-2
2-金刚烷醇
+
29542-62-9
2,2'-联金刚烷
+
70334-00-8
+
114332-09-1
反应条件
in diethyl ether T=0°C; 0.25 h; without aceton-d6; several other aldehydes, ketones and acyl chlorides.; Product distribution;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976
666-52-4
氘代丙酮
+
114332-05-7
→
反应条件
281-23-2
金刚烷
+
700-57-2
2-金刚烷醇
+
29542-62-9
2,2'-联金刚烷
+
114332-09-1
反应条件
in diethyl ether T=0°C; 15 h; Further byproducts given. Yields of byproduct given;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976
114332-05-7
→
反应条件
29542-62-9
2,2'-联金刚烷
+
76283-44-8
反应条件
1,4-dioxane 6 h;
参考文献
Bochmann, Manfred; Wilkinson, Geoffrey; Young, Brent G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1980 , p. 1879 - 1887
666-52-4
氘代丙酮
+
114332-05-7
→
反应条件
281-23-2
金刚烷
+
700-57-2
2-金刚烷醇
+
29542-62-9
2,2'-联金刚烷
+
70334-00-8
+
114332-09-1
反应条件
in diethyl ether T=0°C; 0.25 h; without aceton-d6; several other aldehydes, ketones and acyl chlorides.; Product distribution;
参考文献
Yurchenko, A. G.; Fedorenko, T. V.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 5 p. 875 - 880
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 5 p. 970 - 976