过钌酸四丙胺盐(TPAP)合成路线 （共 21 条）
反应条件
sodium carbonate in water mixt. of RuCl3 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; elem. anal.;
参考文献
Bailey, Alan J.; Griffith, William P.; Mostafa, Sahar I.; Sherwood, Paul A.
Inorganic Chemistry, 1993 , vol. 32, p. 268 - 271
反应条件
K2CO3 stirred at 0°C for 3 h; washed with ice-cold H2O, dried in vac.; elem. anal.;
参考文献
Dengel, Andrew C.; Griffith, William P.
Inorganic Chemistry, 1991 , vol. 30, p. 869 - 871
反应条件
in water stirring of hydrated RuCl3 and NaIO4 in H2O overnight; addn. to an aq. soln. of n-Pr4NOH containing NaOH at 0-5°C under an atmosphere of O2;; ppt. was removed every 20 min, washed with ice-cold water, and dried under vac.;;
参考文献
Griffith, William P.; Ley, Steven V.; Whitcombe, Gwynne P.; White, Andrew D.
Journal of the Chemical Society, Chemical Communications, 1987 , p. 1625 - 1627
反应条件
4-methylmorpholine N-oxide; silica gel in dichloromethane
参考文献
Kim, Ronald M.; Chang, Jiang; Chapman, Kevin T.; Mills, Sander G.
Patent: US2002/193407 A1, 2002 ;
参考文献
Astra Aktiebolag
Patent: US6043236 A1, 2000 ;
反应条件
in dichloromethane; water addn. of aq. NaOCl soln. to soln. of (n-Pr4)N(RuO4) in CH2Cl2 under stirring at 25°C; pH 9; generated in soln.; not isolated;
参考文献
Gonsalvi, Luca; Arends, Isabel W.C.E.; Sheldon, Roger A.
Chemical Communications, 2002 , # 3 p. 202 - 203
反应条件
4-methylmorpholine N-oxide; silica gel in dichloromethane; acetonitrile
参考文献
Gong, Leyi; Grupe, Andrew; Peltz, Gary Allen
Patent: US2002/52397 A1, 2002 ;
US 20020052397 A1
反应条件
molecular sieves in dichloromethane
参考文献
Bridger, Gary; Kaller, Al; Harwig, Curtis; Skerlj, Renato; Bogucki, David; Wilson, Trevor R.; Crawford, Jason; McEachern, Ernest J.; Atsma, Bem; Nan, Siqiao; Zhou, Yuanxi; Schols, Dominique; Smith, Christopher D.; Di Fluri, Maria R.
Patent: US2004/19058 A1, 2004 ;
US 20040019058 A1
反应条件
4-methylmorpholine N-oxide; silica gel in dichloromethane
参考文献
Beck, James P.; Pechulis, Anthony D.; Harms, Arthur E.
Patent: US2002/91134 A1, 2002 ;
US 20020091134 A1
反应条件
silica gel in dichloromethane
参考文献
COCENSYS, INC.
Patent: EP808325 B1, 2001 ;
