2-甲基-3-丁烯-2-醇合成路线 （共 471 条）
反应条件
bei folgendem Verseifen;
参考文献
Lennartz
Zeitschrift fuer Naturforschung, 1946 , vol. 1, p. 689
参考文献
Lebedewa; Almaschi
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 904,905,907;engl.Ausg.S.876,877,878
参考文献
Lebedewa; Almaschi
Zhurnal Obshchei Khimii, 1953 , vol. 23, p. 994,998;engl.Ausg.S.1041
反应条件
oxalic acid 5 h; Heating; Mechanism;
参考文献
Bertrand, M.; Waegell, B.; Zahra, J. P.
Bulletin de la Societe Chimique de France, 1991 , # 6 p. 904 - 910
反应条件
sulfuric acid T=25°C; acid-catalyzed isomerization, dehydratation and decomposition of isopentenols, retro-Prince reaction; Product distributionRate constant;
参考文献
Ryabova, R. S.; Osipova, G. F.
Russian Chemical Bulletin, 1994 , vol. 43, # 2 p. 311 - 313
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1994 , # 2 p. 332 - 334
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; bis(η3-allyl-μ-chloropalladium(II)); formic acid methyl ester; polyoxyethanyl-α-tocopheryl sebacate; potassium carbonate in water T=20°C; 20 h; Inert atmosphere; regioselective reaction;
参考文献
Nishikata, Takashi; Lipshutz, Bruce H.
Organic Letters, 2009 , vol. 11, # 11 p. 2377 - 2379
反应条件
1.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere 1.2: 1 h / 0 °C / Inert atmosphere 2.1: bis(bicyclo[2.2.1]hepta-2,5-diene)dichlorodirhodium / tetrahydrofuran / 0.5 h / 25 °C / Inert atmosphere View Scheme
参考文献
Arnold, Jeffrey S.; Cizio, Gregory T.; Nguyen, Hien M.
Organic Letters, 2011 , vol. 13, # 20 p. 5576 - 5579
参考文献
Akzo NV
Patent: US4705888 A1, 1987 ;
反应条件
palladium diacetate; toluene-4-sulfonic acid; triphenylphosphine in dichloromethane T=100 - 120°C; P=20685.9 Torr; 48 h; further reagents and conditions;
参考文献
Xiao, Wen-Jing; Alper, Howard
Journal of Organic Chemistry, 1998 , vol. 63, # 22 p. 7939 - 7944
反应条件
1: 83 percent / Cu / 1 h / 120 °C 2: 67 percent / Bu3SnH / 0.5 h / 80 °C View Scheme
参考文献
Kotora, M.; Hajek, M.; Ameduri, B.; Boutevin, B.
Journal of Fluorine Chemistry, 1994 , vol. 68, # 1 p. 49 - 56
