2-甲基-3-丁烯-2-醇合成路线 （共 471 条）
反应条件
1: 1.2 g / BF3-etherate / dioxane / 24 h / 60 °C 2: 140 mg / DDQ / benzene / 6 h / Heating View Scheme
参考文献
Iyer, P. R.; Iyer, C. S. Rukmani; Prasad, K. J. Rajendra
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 6 p. 535 - 538
反应条件
1: 68 percent / PBr3 / -20 °C 2: 1.) Mg, 2.) 10percent CuI / 1.) THF, 35-40 deg C, 15 min, 2.) room temp., overnight View Scheme
参考文献
Parr, William J. E.
Journal of Chemical Research, Miniprint, 1981 , # 11 p. 4101 - 4130
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Schneider; Cloux; Foti; Kovats
Synthesis, 1990 , # 11 p. 1027 - 1031
参考文献
Pasanen,P.; Pihlaja,K.
Acta Chemica Scandinavica (1947-1973), 1971 , vol. 25, p. 1908 - 1910
反应条件
1: 35 mg / BF3-etherate / dioxane / 24 h / 60 °C 2: 160 mg / conc. HCl / acetic acid / 1 h / Heating 3: 1.) NBS, dibenzoylperoxide 2.) pyridine / 1.) carbon tetrachloride, 3 h reflux 2.) 2h reflux or DDQ, benzene View Scheme
参考文献
Iyer, P. R.; Iyer, C. S. Rukmani; Prasad, K. J. Rajendra
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 6 p. 535 - 538
反应条件
(i) BF3*Et2O, dioxane, (ii) Ag2O, Et2O; Multistep reaction;
参考文献
Burnett,A.R.; Thomson,R.H.
Journal of the Chemical Society [Section] C: Organic, 1968 , p. 850 - 853
反应条件
pyridine; chloroform
参考文献
Straus; Kuehnel
Chemische Berichte, 1933 , vol. 66, p. 1834,1839
反应条件
1.1: BF3*Et2O / dioxane / 0.17 h / 25 °C 1.2: 10 percent / dioxane / 2.5 h / 25 °C 2.1: polystyrene-based selenenyl bromide resin / CH2Cl2 / 0.33 h / 0 - 25 °C 2.2: H2O2 / tetrahydrofuran / 0.33 h / 25 °C View Scheme
参考文献
Fujimoto, Tomoko; Nomura, Taro
Heterocycles, 1984 , vol. 22, # 5 p. 997 - 1003
反应条件
chlorine T=22.84°C; P=760 Torr; UV-irradiationInert atmosphereGas phase; Kinetics; PressureReagent/catalyst;
参考文献
Takahashi, Kenshi; Xing, Jia-Hua; Hurley, Michael D.; Wallington, Timothy J.
Journal of Physical Chemistry A, 2010 , vol. 114, # 12 p. 4224 - 4231
反应条件
[Pd(C,N-C6H4CH2NMe2)Cl]2; toluene-4-sulfonic acid in methanol; dimethyl sulfoxide T=50°C;
参考文献
Dutheuil, Guillaume; Selander, Nicklas; Szabo, Kalman J.; Aggarwal, Varinder K.
Synthesis, 2008 , # 14 SPEC. ISS. art. no. C02308SS, p. 2293 - 2297
