2-甲基-3-丁烯-2-醇合成路线 （共 471 条）
反应条件
acetic anhydride; triethylamine in dichloromethane; water
参考文献
The Dow Chemical Company
Patent: US4667050 A1, 1987 ;
参考文献
Young; Webb
Journal of the American Chemical Society, 1951 , vol. 73, p. 780
Full Text View citing articles Show Details
Nesmejanow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1949 , p. 623,627136,138
Chem.Abstr., 1950 , p. 3920
反应条件
1: hydrogen chloride / 0 °C
2: NaHCO3 / 45 °C
3: hydrogen chloride / 0 °C
4: glacial acetic acid / 25 °C / dann bei 50-60grad
View Scheme
参考文献
Nasarow; Aserbajew
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 419,421
Chem.Abstr., 1949 , p. 114
反应条件
aluminum oxide; di-isopropyl ether; silica gel; thorium(IV) dioxide
参考文献
Eastman Kodak Co.
Patent: US2685598 , 1951 ;
反应条件
mesoporous silica containing bimetallic Cu-Al (CuAl-KIT-5) in 1,2-dichloro-ethane
T=60°C; 12 h;
参考文献
Varghese, Shaji; Anand, Chokkalingam; Dhawale, Dattatray; Mane, Gurudas P.; Wahab, Mohammad A.; Mano, Ajayan; Raj, George Allen Gnana; Nagarajan, Samuthira; Vinu, Ajayan
ChemCatChem, 2013 , vol. 5, # 4 p. 899 - 902
反应条件
1: 92 percent / BF3*Et2O / dioxane / Heating
2: H2O, alkali
3: 94 percent / Cu(OAc)2 / propan-2-ol
4: 91 percent / PPE
5: EtSNa / dimethylformamide
6: DDQ / 1,2-dichloro-benzene
View Scheme
参考文献
Anand; Selvapalam
Chemical Communications, 1996 , # 2 p. 199 - 200
反应条件
CuAl-SBA-15 in cyclohexane
T=85°C; 6 h;
参考文献
Varghese, Shaji; Anand, Chokkalinkam; Dhawale, Dattatray; Mano, Ajayan; Balasubramanian, Veerappan V.; Raj, George Allen Gnana; Nagarajan, Samuthira; Wahab, Mohammad A.; Vinu, Ajayan
Tetrahedron Letters, 2012 , vol. 53, # 42 p. 5656 - 5659
反应条件
1: 68 percent / PBr3 / -20 °C
2: 1.) Mg, 2.) 10percent CuI / 1.) THF, 35-40 deg C, 15 min, 2.) room temp., overnight
View Scheme
参考文献
Parr, William J. E.
Journal of Chemical Research, Miniprint, 1981 , # 11 p. 4101 - 4130
反应条件
copper(l) iodide; boron trifluoride diethyl etherate
Yield given. Yields of byproduct given;
参考文献
Yamamoto, Yoshinori; Yamamoto, Shinichi; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1980 , vol. 102, # 7 p. 2318 - 2325
反应条件
1: Et3N / CH2Cl2 / Ambient temperature; several hours
2: 1.) n-Bu3SnH; 2.) H2O2 / 1.) AIBN / 1.) benzene, reflux, 1-2 h; 2.) MeOH, THF, Na2CO3, reflux 5 h
View Scheme
参考文献
Nishiyama, Hisao; Kitajima, Toshio; Matsumoto, Makoto; Itoh, Kenji
Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2298 - 2300
