2-甲基-3-丁烯-2-醇合成路线 （共 471 条）
反应条件
palladium diacetate; sodium hydrogencarbonate in N,N-dimethyl-formamide
T=120°C; 3 h; other allylic alcohol;
参考文献
Garcias; Ballester; Saa
Tetrahedron Letters, 1991 , vol. 32, # 52 p. 7739 - 7742
反应条件
sulfuric acid; copper(II) sulfate
参考文献
Nasarow; Jufit
Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 783,786;engl.Ausg.S.770
反应条件
MoCl2(acetylacetonate)2; trimethylsilylazide; silver trifluoromethanesulfonate in dichloromethane
0.166667 h; Ambient temperature;
参考文献
Malkov, Andrei V.; Spoor, Paul; Vinader, Victoria; Kocovsky, Pavel
Journal of Organic Chemistry, 1999 , vol. 64, # 14 p. 5308 - 5311
反应条件
ascorbate; citric acid
12 h;
参考文献
Ashok Kumar; Tiwari, Ashok K.; Saidachary; Kishor, Chandan; Kumar, D. Anand; Ali, Zehra; Sridhar; Addlagatta, Anthony; Raju, B. China
Medicinal Chemistry Research, 2014 , vol. 23, # 6 p. 2821 - 2833
反应条件
1: With C20H17ClPdSe2; water; toluene-4-sulfonic acid; 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in methanol; dimethyl sulfoxide
T=50°C; 20 h;
2: With (SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium in methanol; dichloromethane; dimethyl sulfoxide
20 h; Inert atmosphereReflux;
参考文献
Selander, Nicklas; Szabo, Kalman J.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 13 p. 2045 - 2051
反应条件
1: 1,1-dimethylallyl alcohol With potassium hydride in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 0.166667 h;
2: daikon-phytoalexin in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 1 h; regioselective reaction;
参考文献
Yamada, Fumio; Shinmyo, Daisuke; Nakajou, Masahiro; Somei, Masanori
Heterocycles, 2012 , vol. 86, # 1 p. 435 - 453
反应条件
1: conc. HCl / -10 - 0 °C
2: 1.) magnesium / 1.) ether, 0-5 deg C, 2.) ether, 20 deg C, 3 h
View Scheme
参考文献
Laduranty, Joelle; Barbot, Francis; Miginiac, Leone
Bulletin de la Societe Chimique de France, 1989 , # 6 p. 850 - 855
反应条件
sodium hydride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran
T=65°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
1: pyridine / diethyl ether / Heating
2: 1.) NaH, 2.) Bu4N<Fe(CO)3NO> / 1.) THF, 10 min, 2.) THF, reflux, 12 h
View Scheme
参考文献
Xu, Yuanyao; Zhou, Bo
Journal of Organic Chemistry, 1987 , vol. 52, # 6 p. 974 - 977
反应条件
sodium hydride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran
T=65°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
