2-甲基-3-丁烯-2-醇合成路线 （共 471 条）
反应条件
cerium (III) nitrate hexahydrate; dihydrogen peroxide; lithium bromide in water
T=65 - 70°C; 10 h;
参考文献
Nikishin; Sokova; Kapustina
Russian Chemical Bulletin, 2012 , vol. 61, # 2 p. 459 - 463
Izv. Akad. Nauk, Ser. Khim., 2012 , # 2 p. 456 - 460,5
参考文献
Fekner, Tomasz; Mueller-Bunz, Helge; Guiry, Patrick J.
Organic Letters, 2006 , vol. 8, # 22 p. 5109 - 5112
参考文献
United Gas Improv.Co.
Patent: US2246545 , 1938 ;
参考文献
Astin,K.B.; Whiting,M.C.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1976 , p. 1157 - 1160
反应条件
Grubb's 2nd generation catalyst in dichloromethane
olefin cross-metathesis; 12 h; Heating; Title compound not separated from byproducts;
参考文献
Morrill, Christie; Grubbs, Robert H.
Journal of Organic Chemistry, 2003 , vol. 68, # 15 p. 6031 - 6034
反应条件
1: conc. HCl / -10 - 0 °C
2: 1.) magnesium / 1.) ether, 0-5 deg C, 2.) ether, 20 deg C, 3 h
3: HgCl2, H2O / diethyl ether / 24 h / Ambient temperature
View Scheme
参考文献
Laduranty, Joelle; Barbot, Francis; Miginiac, Leone
Bulletin de la Societe Chimique de France, 1989 , # 6 p. 850 - 855
反应条件
boron trifluoride diethyl etherate in 1,4-dioxane
T=20°C; 72 h;
参考文献
Helesbeux, Jean-Jacques; Duval, Olivier; Guilet, David; Seraphin, Denis; Rondeau, David; Richomme, Pascal
Tetrahedron, 2003 , vol. 59, # 27 p. 5091 - 5104
反应条件
in formic acid; water
T=80°C; 0.333333 h;
参考文献
Nicolaou; Pfefferkorn; Roecker; Cao; Barluenga; Mitchell
Journal of the American Chemical Society, 2000 , vol. 122, # 41 p. 9939 - 9953
参考文献
Francis,T.; Thorne,M.P.
Canadian Journal of Chemistry, 1976 , vol. 54, p. 24 - 30
反应条件
Montmorillonite K 10
T=20°C; 216 h; Further byproducts given;
参考文献
Desaubry, Laurent; Nakatani, Yoichi; Ourisson, Guy
Tetrahedron Letters, 2003 , vol. 44, # 36 p. 6959 - 6961
