2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine in tetrahydrofuran T=60°C; Sonogashira coupling; 20 h; Inert atmosphere;
参考文献
Juriek, Michal; Felici, Marco; Contreras-Carballada, Pablo; Lauko, Jan; Bou, Sandra Rodriguez; Kouwer, Paul H. J.; Brouwer, Albert M.; Rowan, Alan E.
Journal of Materials Chemistry, 2011 , vol. 21, # 7 p. 2104 - 2111
反应条件
1: triethylamine; copper(l) iodide; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 12 h / 75 °C / |Inert atmosphere 2: copper(ll) bromide / nitromethane / 12 h / 20 °C / |Darkness 3: triethylamine; copper(l) iodide; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 12 h / 80 °C / |Inert atmosphere 4: chloroform / 2 h / |UV-irradiation View Scheme
参考文献
Gschneidtner, Tina A.; Moth-Poulsen, Kasper
Tetrahedron Letters, 2013 , vol. 54, # 40 p. 5426 - 5429
反应条件
N,N-dimethyl-aniline T=150°C;
参考文献
Petrow; Lagutschewa
Zhurnal Obshchei Khimii, 1951 , vol. 21, p. 1247,1248,1251;engl.Ausg.S.1361,1362,1364
反应条件
methanol; boron trifluoride diethyl etherate; mercury(II) oxide T=45 - 55°C; Reagens 4: Trichloressigsaeure;
参考文献
Froning; Hennion
Journal of the American Chemical Society, 1940 , vol. 62, p. 654
Full Text Show Details
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 219
Chem.Abstr., 1942 , p. 746
反应条件
in Gegenwart eines aus rotem HgO, Borfluorid-aetherat und Trichloressigsaeure durch Erhitzen in Methanol dargestellten Katalysators;
参考文献
Froning; Hennion
Journal of the American Chemical Society, 1940 , vol. 62, p. 654
Full Text Show Details
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 195
Chem.Abstr., 1942 , p. 743
Chem. Zentralbl., 1942 , vol. 113, # I p. 739
反应条件
Ph3PAuMe; sulfuric acid in methanol; water T=70°C; 2 h;
参考文献
Angewandte Chemie - International Edition, , vol. 41, # 23 p. 4563 - 4565
反应条件
vanadium-montmorillonite in xylene 1 h; Heatingother α-acetylenic alcohols;
参考文献
Tetrahedron Letters, , vol. 31, # 51 p. 7521 - 7522
反应条件
bis(2-methylpropenyl)(1,2-bis(diphenylphosphino)ethane)ruthenium T=70°C; 2 h; Yield given;
参考文献
Chemical Communications, , # 13 p. 1201 - 1202
反应条件
polyvanadioorganosiloxane (3.1percent V) in xylene T=150 - 160°C; 6 h; Further byproducts given;
参考文献
Journal of Organic Chemistry USSR (English Translation), , p. 21 - 28
Zhurnal Organicheskoi Khimii, , vol. 16, # 1 p. 23 - 31
反应条件
sulfuric acid; pentane 1.) 20 grad C, 16 h; 2.) room temperature, 40 h; Yield given. Multistep reaction;
参考文献
Tetrahedron Letters, , vol. 25, # 2 p. 189 - 192
